Neutron Studies of the Structure of Non-Polar Magnetic Fluids with Surfactant Excess

L. A. Bulavin; A. V. Nagornyi; V. I. Petrenko; M. V. Avdeev; L. Alm´asy; L. Rosta; V. L. Aksenov

doi:10.15407/ujpe58.12.1143

Neutron Studies of the Structure of Non-Polar Magnetic Fluids with Surfactant Excess

Authors

L. A. Bulavin Taras Shevchenko National University of Kyiv, Faculty of Physics
A. V. Nagornyi Taras Shevchenko National University of Kyiv, Faculty of Physics, Joint Institute for Nuclear Research
V. I. Petrenko Taras Shevchenko National University of Kyiv, Faculty of Physics, Joint Institute for Nuclear Research
M. V. Avdeev Joint Institute for Nuclear Research
L. Alm´asy Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences
L. Rosta Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences
V. L. Aksenov B.P. Konstantinov Petersburg Nuclear Physics Institute, Joint Institute for Nuclear Research

DOI:

https://doi.org/10.15407/ujpe58.12.1143

Keywords:

magnetic ﬂuids, ferroﬂuids, small-angle neutron scattering, decalin

Abstract

Non-polar magnetic ﬂuid systems with an excess of surfactants have been studied with the use of the small-angle neutron scattering technique. Two types of highly stable ferroﬂuids, magnetite/oleic acid/decalin and magnetite/myristic acid/decalin, with a low (of about 1 vol.%) magnetite content and various acid fractions (up to 25 vol.%) are examined. The aggregation of magnetic particles and surfactant molecules is shown not to occur in the indicated concentration range of the acid molecule excess. The experimental results testify to a change of the interaction between the molecules of oleic and myristic acids in the free (non-adsorbed) state, when they are dissolved in magnetic ﬂuids, and in their solutions in decalin without magnetic particles.

References

B. Berkovsky and V. Bashtovoi, Magnetic Fluids and Applications. Handbook (Begell House, New York, 1996).

L. Vekas, M.V. Avdeev, and D. Bica, in Magnetic Nanofluids: Synthesis and Structure. Nanoscience and Its Applications in Biomedicine, edited by D. Shi (Springer, Berlin, 2009), p. 645.

U. H¨afeli and M. Zborowski, J. Magn. Magn. Mater. 321, 10 (2009).

https://doi.org/10.1016/j.jmmm.2009.03.008

V.E. Fertman, Magnetic Fluids (Vysheishaya Shkola, Minsk, 1988) (in Russian).

S. Taketomi and S. Chikazumi, Magnetic Fluids – Principle and Application (Nikkan Kogyo Shinbun, Tokyo, 1988) (in Japanese).

V.I. Petrenko, M.V. Avdeev, V.L. Aksenov et al., Poverkhnost Rentgen. Sinkhrotron. Neitron. Issled. 2, 92 (2009).

V.I. Petrenko, M.V. Avdeev, V.L. Aksenov et al., Solid State Phenom. 152, 198 (2009).

https://doi.org/10.4028/www.scientific.net/SSP.152-153.198

V.I. Petrenko, M.V. Avdeev, L. Alm’asy et al., Coll. Surf. A 337, 91 (2009).

https://doi.org/10.1016/j.colsurfa.2008.12.001

M.V. Avdeev, I.A. Bodnarchuk, V.I. Petrenko et al., Zh. Fiz. Khim. 83, 7 (2009).

V.I. Petrenko, M.V. Avdeev, V.M. Garamus et al., Coll. Surf. A 369, 160 (2010).

https://doi.org/10.1016/j.colsurfa.2010.08.023

M.V. Avdeev and V.L. Aksenov, Usp. Fiz. Nauk 180, 10 (2010).

https://doi.org/10.3367/UFNr.0180.201010a.1009

V.L. Aksenov, M.V. Avdeev, A.V. Shulenina et al., Kristallografiya 56, 848 (2011).

V.Yu. Bezzabotnov, L. Cser, T. Grosz et al., J. Phys. Chem. 96, 976 (1992).

https://doi.org/10.1021/j100181a079

G. Jancso, L. Cser, T. Grosz et al., Pure Appl. Chem. 66, 515 (1994).

https://doi.org/10.1351/pac199466030515

L. Cser, B. Farago, T. Grosz et al., Physica B 180, 848 (1992).

https://doi.org/10.1016/0921-4526(92)90489-F

M.V. Avdeev, D. Bica, L. Vekas et al., J. Coll. Interface Sci. 334, 37 (2009).

https://doi.org/10.1016/j.jcis.2009.03.005

J. Bloustine, T. Virmani, G.M. Thurston et al., Phys. Rev. Lett. 96, 087803 (2006).

https://doi.org/10.1103/PhysRevLett.96.087803

Downloads

Published

2018-10-11

How to Cite

Bulavin, L. A., Nagornyi, A. V., Petrenko, V. I., Avdeev, M. V., Alm´asy, L., Rosta, L., & Aksenov, V. L. (2018). Neutron Studies of the Structure of Non-Polar Magnetic Fluids with Surfactant Excess. Ukrainian Journal of Physics, 58(12), 1143. https://doi.org/10.15407/ujpe58.12.1143

Download Citation

Issue

Vol. 58 No. 12 (2013)

Section

Soft matter

License

Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine

The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:

1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.

2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.

3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.

4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.

5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.

6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.