Ламелярно-ланцюгові гідрогелі: особливості структури

Автор(и)

  • Yu.F. Zabashta Taras Shevchenko National University of Kyiv, Faculty of Physics
  • V.I. Kovalchuk Taras Shevchenko National University of Kyiv, Faculty of Physics
  • P. Kopčanský Institute of Experimental Physics, Slovak Academy of Sciences
  • I. Safarik Biology Centre, Czech Academy of Sciences
  • M.M. Lazarenko Taras Shevchenko National University of Kyiv, Faculty of Physics
  • L.Yu. Vergun Taras Shevchenko National University of Kyiv, Faculty of Physics
  • L.A. Bulavin Taras Shevchenko National University of Kyiv, Faculty of Physics

DOI:

https://doi.org/10.15407/ujpe68.8.536

Ключові слова:

гiдрогель, ламелярно-ланцюгова сiтка, малокутове рентгенiвське розсiяння

Анотація

Розглядається можливiсть створення на основi бiнарного водного розчину полiмерних та олiгомерних молекул гiдрогелiв нового типу – ламелярно-ланцюгових – iз каркасом пiдвищеної жорсткостi. Запропоновано гiпотетичну модель такого каркасу, структурними елементами якого є олiгомернi ламели та полiмернi ланцюги. Цi елементи з’єднуються завдяки тому, що кiнцi полiмерних ланцюгiв втягуються в пори ламел. Отримано формулу для вiльної енергiї такої системи. Показано, що збiльшення концентрацiї полiмера має привести до взаємного зближення ламел. Цей висновок узгоджується з результатами проведеного методом малокутового розсiяння рентгенiвських променiв експерименту, в якому дослiджувались бiнарнi воднi розчини полiмера (полiетиленглiколя) та олiгомера (додецилсульфата натрiю) з рiзними концентрацiями.

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Опубліковано

2023-10-02

Як цитувати

Zabashta, Y., Kovalchuk, V., Kopčanský, P., Safarik, I., Lazarenko, M., Vergun, L., & Bulavin, L. (2023). Ламелярно-ланцюгові гідрогелі: особливості структури. Український фізичний журнал, 68(8), 536. https://doi.org/10.15407/ujpe68.8.536

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