Термо-оптичні ефекти в плазмонних металевих наноструктурах

Автор(и)

  • O.A. Yeshchenko Taras Shevchenko National University of Kyiv, Physics Department http://orcid.org/0000-0001-8927-5673
  • A.O. Pinchuk Department of Physics and Energy Sciences, University of Colorado at Colorado Springs

DOI:

https://doi.org/10.15407/ujpe66.2.112

Ключові слова:

металевi наночастинки, поверхневий плазмонний резонанс, температурнi ефекти, електрон-фононне розсiяння, теплове розширення наночастинки, плазмонна фотолюмiнесценцiя, нагрiвання свiтлом

Анотація

Представлено огляд ефектiв, пов’язаних iз впливом температури на поверхневий плазмонний резонанс (ППР) в наночастинках благородних металiв у дiапазонi 77–1190 K. Виявлено, що пiдвищення температури приводить до помiтного червоного зсуву, а також – до розширення ППР у наночастинках (НЧ). Показано, що теплове розширення та збiльшення частоти електрон-фононного розсiяння, що вiдбуваються при збiльшеннi температури, є домiнуючими фiзичними механiзмами, що приводять до червоного зсуву та розширення ППР. Виявлено ефект сильної температурної залежностi, пiдсиленої поверхневими плазмонами фотолюмiнесценцiї наночастинок срiбла (Ag) та мiдi (Cu). Квантовий вихiд фотолюмiнесценцiї наночастинок Ag зменшується при пiдвищеннi температури внаслiдок зменшення фактора плазмонного пiдсилення, зумовленого збiльшенням частоти електрон-фононного розсiяння. У той же час, було виявлено аномальну залежнiсть вiд температури фотолюмiнесценцiї наночастинок Cu, а саме – збiльшення квантового виходу фотолюмiнесценцiї зi збiльшенням температури. Показано, що спiльний вплив ППР та мiжзонних переходiв вiдiграє визначальну роль у цьому ефектi. Дослiджено також зумовлений поверхневими плазмонами лазерний нагрiв щiльного 2D-масиву наночастинок Au на дiелектричнiй пiдкладинцi та наночастинок Au у водних колоїдних розчинах. Показано, що наближення частоти лазера до ППР приводить до сильного нагрiву наночастинок Au. Такий резонансний ефект доводить плазмонний характер лазерного нагрiву металевих НЧ. Спостережуваний рiзкий блакитний зсув поверхневого плазмонного резонансу в НЧ Au в колоїдному розчинi при температурах, що перевищують температуру кипiння води, свiдчить про утворення локальних нанорозмiрних бульбашок водяної пари навколо наночастинок.

Біографії авторів

O.A. Yeshchenko, Taras Shevchenko National University of Kyiv, Physics Department

Physics Department

A.O. Pinchuk, Department of Physics and Energy Sciences, University of Colorado at Colorado Springs

Department of Physics and Energy Sciences

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2021-03-04

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Yeshchenko, O., & Pinchuk, A. (2021). Термо-оптичні ефекти в плазмонних металевих наноструктурах. Український фізичний журнал, 66(2), 112. https://doi.org/10.15407/ujpe66.2.112

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