Adiabatic Compressibility of Aqueous Solutions of Polyols
DOI:
https://doi.org/10.15407/ujpe66.9.780Keywords:
adiabatic compressibility, polyols, aqueous solutionsAbstract
According to experimental data on the density of polyol solutions and the propagation velocity of ultrasonic waves in them, the adiabatic compressibilities of the aqueous solutions of erythritol, xylitol, sorbitol, and mannitol are calculated. For all examined solutions, the temperature dependence of the adiabatic compressibility is found to pass through a minimum. As the polyol concentration in water increases, the minimum of the adiabatic compressibility shifts toward lower temperatures. The temperature values corresponding to the minimum of the molar adiabatic compressibility are calculated. The concentration dependences of this parameter are shown to be linear. The presence of a special point for the studied aqueous solutions of polyols is established.
References
L.A. Bulavin, V.L. Kulinskii, N.P. Malomuzh. The singularity of the diameter for the binodal in terms of the entropy-temperature for atomic and molecular liquids. Ukr. J. Phys. 55, 1282 (2010).
L.A. Bulavin, V.L. Kulinskii. Generalized principle of corresponding states and the scale invariant mean-field approach. J. Chem. Phys. 133, 134101 (2010).
L.A. Bulavin, V.L. Kulinskii, N.P. Malomuzh. Peculiarities in the behavior of the entropy diameter for molecular liquids as the reflection of molecular rotations and the excluded volume effects. J. Mol. Liq. 161, 19 (2011).
L.A. Bulavin, V.L. Kulinskii. The unified picture for the classical laws of Batschinski and the rectilinear diameter for molecular fluids. J. Phys. Chem. B 115, 6061 (2011).
V. Pogorelov, I. Doroshenko, G. Pitsevich, V. Balevicius, V. Sablinskas, B. Krivenko, L.G.M. Pettersson. From clusters to condensed phase – FTIR studies of water. J. Mol. Liq. 235, 7 (2017).
A. Vasylieva, I. Doroshenko, Ye. Vaskivskyi, Ye. Chernolevska, V. Pogorelov. FTIR study of condensed water structure. J. Mol. Struct. 1167, 232 (2018).
P. Jedlovszky, L.B. P´artay, A.P. Bart´ok, V.P. Voloshin, N.N. Medvedev, G. Garberoglio, R. Vallauri. Structural and thermodynamic properties of different phases of supercooled liquid water. J. Chem. Phys. 128, 244503 (2008).
H.E. Stanley. Understanding static and dynamic heterogeneities in confined water. Z. Phys. Chem. 223, 939 (2009).
L.A. Bulavin, Y.F. Zabashta, A.M. Khlopov, A.V. Khorol’skii. Molecular mechanism of the viscosity of aqueous glucose solutions. Russ. J. Phys. Chem. 91, 89 (2017).
L.A. Bulavin, A.V. Chalyi, O.I. Bilous. Anomalous propagation and scattering of ultrasound in 2-propanol water solution near its singular point. J. Mol. Liq. 235, 24 (2017).
V. Pogorelov, A. Yevglevsky, I. Doroshenko, L. Berezovchuk, Yu. Zhovtobryuch. Nanoscale molecular clusters and vibrational relaxation in simple alcohols. Superlat. Microstruct. 44, 571 (2008).
P. Golub, V. Pogorelov, I. Doroshenko. The structural peculiarities of liquid n-heptanol and n-octanol. J. Mol. Liq. 169, 80 (2012).
O.V. Khorolskyi. The nature of viscosity of polyvinyl alcohol solutions in dimethyl sulfoxide and water. Ukr. J. Phys. 62, 858 (2017).
L.A. Bulavin, A.M. Getalo, O.P. Rudenko, O.V. Khorolskyi. Influence of fluorination on the physical properties of normal aliphatic alcohols. Ukr. J. Phys. 60, 428 (2015).
N.A. Atamas, A.M. Yaremko, L.A. Bulavin, V.E. Pogorelov, S. Berski, Z. Latajka, H. Ratajczak, A. AbkowiczBie´nko. Anharmonic interactions and Fermi resonance in the vibrational spectra of alcohols. J. Mol. Struct. 605, 187 (2002).
M.P. Kozlovskii. Free energy of 3D Ising-like system near the phase transition point. Condens. Matter Phys. 12, 151 (2009).
M.P. Kozlovskii, R.V. Romanik. Influence of an external field on the critical behavior of the 3D Ising-like model. J. Mol. Liq. 167, 14 (2012).
L.A. Bulavin, V.Ya. Gotsulskiy, V.E. Chechko. Light scattering by aqueous solution of alcohols near their singular points. Ukr. J. Phys. 59, 881 (2014).
V. Gotsulskiy, V. Chechko, Y. Melnik. The origin of light scattering by aqueous solutions of alcohols in vicinities of their singular points. Ukr. J. Phys. 60, 780 (2019).
L. Bulavin, V. Gotsulskiy, N. Malomuzh, M. Stiranets. Refractometry of water–ethanol solutions near their contraction point. Ukr. J. Phys. 60, 1108 (2019).
L. Bulavin, O. Bilous, O. Svechnikova. Relaxation time of concentration fluctuations in a vicinity of the critical stratification point of the binary mixture n-pentanol–nitromethane. Ukr. J. Phys. 61, 879 (2019).
L. Bulavin, O. Bilous, A. Balega, O. Svechnikova. Anomalies of the sound absorption coefficient for binary solutions with a critical stratification temperature. Ukr. J. Phys. 63, 308 (2018).
I.G. Mykhailov, V.A. Soloviov, Yu.P. Sirnikov. Fundamentals of Molecular Acoustics (Nauka, 1964) (in Russian).
O.V. Grineva, E.V. Belyaeva. Structure of water–glycine solutions in saturated and near-saturated regions according to compressibility data. J. Struct. Chem. 52, 1139 (2011).
Downloads
Published
How to Cite
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.