Light Scattering by Aqueous Solutions of Alcohols Near Their Singular Points

L. A. Bulavin; V. Ya. Gotsulskiy; V. E. Chechko

doi:10.15407/ujpe59.09.0881

Light Scattering by Aqueous Solutions of Alcohols Near Their Singular Points

Authors

L. A. Bulavin Taras Shevchenko National University of Kyiv, Chair of Molecular Physics
V. Ya. Gotsulskiy Taras Shevchenko National University of Kyiv, Chair of Molecular Physics
V. E. Chechko I.I. Mechnikov National University of Odesa, Scientific and Research Institute of Physics

DOI:

https://doi.org/10.15407/ujpe59.09.0881

Keywords:

light scattering, dilute aqueous solutions of alcohols, low-concentration peak, ethylene glycol

Abstract

The dependence of the position x0 of the low-concentration peak on the curves of light scattering by aqueous solutions of alcohols on their molecular masses has been found. The relevant concentration for ethylene glycol at 20 ∘C is determined and compared with the literature data for the homologous series of methanol. The obtained dependence is linear to an error less than 2%.

References

M.F. Vuks, Light Scattering in Gases, Liquids, and Solutions (Leningrad State Univ., Leningrad, 1977) (in Russian).

G.W. Beer and D.J. Jolly, Opt. Commun. 11, 150 (1974).

https://doi.org/10.1016/0030-4018(74)90205-3

M.A. Anisimov, Critical Phenomena in Liquids and Liquid Crystals (Gordon and Breach, Philadelphia, 1991).

D.I. Mendeleev, Solutions (Izd. Akad. Nauk SSSR, Moscow, 1956) (in Russian).

N.F. Bunkin and F.V. Bunkin, Zh. Eksp. Teor. Fiz. 101, 512 (1992).

D. Subramanian and M.A. Anisimov, J. Phys. Chem. B 115, 9179 (2011).

https://doi.org/10.1021/jp2041795

V.E. Chechko and V.G. Zaremba, Khim. Fiz. 12, 1036 (1993).

G.P. Roshchina and A.S. Kaurova, Ukr. Fiz. Zh. 9, 512 (1964).

H. Tonaka, K. Nakanishi, and H. Tonhara, J. Chem. Phys. 81, 4065 (1983).

https://doi.org/10.1063/1.448150

M.F. Vuks, L.I. Lisnyanskii, and L.V. Shurupova, in Structure and Role of Water in a Living Organism (Leningrad State Univ., Leningrad, 1968), Issue 2, p. 39 (in Russian).

M.F. Vuks and L.V. Shurupova, Zh. Strukt. Khim. 12, 712 (1971).

V.M. Byakov, L.V. Lanshina, O.P. Stepanova, and S.V. Stepanov, Zh. Fiz. Khim. 83, 280 (2009).

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Published

2018-10-24

How to Cite

Bulavin, L. A., Gotsulskiy, V. Y., & Chechko, V. E. (2018). Light Scattering by Aqueous Solutions of Alcohols Near Their Singular Points. Ukrainian Journal of Physics, 59(9), 881. https://doi.org/10.15407/ujpe59.09.0881

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Issue

Vol. 59 No. 9 (2014)

Section

Soft matter

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