Temperature-Induced Features in the Local Structure of Aqueous Monovalent Electrolyte Solutions
Keywords:molecular dynamics, intermolecular interaction energy, local structure, hydrogen bond
The results of researches concerning the temperature influence on the formation of a local structure in infinitely dilute aqueous solutions of monovalent sodium electrolytes are reported. The analysis of experimental data shows that the dissolution of a salt leads to the formation of a local structure in water. The results obtained do not contradict, but significantly complement the results of other experimental studies of dielectric permittivity and those with the use of neutron and infrared spectroscopies.
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