NMR Study of Non-Equilibrium State of Fullerene C60 in N-Methyl-2-Pyrrolidone

Authors

  • O.B. Karpenko O. Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine
  • V.V. Trachevskij G.V. Kurdyumov Institute for Metal Physics, Nat. Acad. of Sci. of Ukraine
  • O.V. Filonenko O.O. Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine
  • V.V. Lobanov O. Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine
  • M.V. Avdeev Joint Institute for Nuclear Research
  • T.V. Tropin Joint Institute for Nuclear Research
  • O.A. Kyzyma Taras Shevchenko National University of Kyiv, Faculty of Physics
  • S.V. Snegir O. Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine

DOI:

https://doi.org/10.15407/ujpe57.8.860

Keywords:

-

Abstract

The results of 1H~NMR researches concerning the interaction between fullerene С60 and N-methyl-2-pyrrolidone (NMP) molecules in an as-prepared solution are reported. By comparing the spectra for pure NMP and the С60-NMP system, system the formation of a complex between fullerene and solvent molecules is revealed, which is responsible for the time-dependent solvatochromic effect discovered earlier. Different magnitudes of chemical shifts for α-, β-, γ-, and α'-protons in the NMP molecules allowed a hypothesis to be put forward that the interaction in the С60-NMP system occurs through the formation of a donor-acceptor bond between the keto-group of an NMP molecule and a fragment of a С60 molecule. The results of quantum chemical simulation for the С60 · NMP complex with a stoichiometric composition of 1:1 testify to a redistribution of the electron density over the system of bonds in an NMP  molecule induced by a С60 molecule.

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Published

2012-08-30

How to Cite

Karpenko О., Trachevskij В., Filonenko О., Lobanov В., Avdeev М., Tropin Т., Kyzyma О., & Snegir С. (2012). NMR Study of Non-Equilibrium State of Fullerene C60 in N-Methyl-2-Pyrrolidone. Ukrainian Journal of Physics, 57(8), 860. https://doi.org/10.15407/ujpe57.8.860

Issue

Vol. 57 No. 8 (2012)

Section

Nanosystems

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