Optical Properties of Conducting Polymer Poly(O-Toluidine)-DBSA Blended with Polyethylene Oxide
DOI:
https://doi.org/10.15407/ujpe63.3.263Abstract
Conducting polymer poly(O-toluidine) (POT) doped with dodecyl benzene sulfonic acid was prepared by the chemical polymerization with the help of ammonium persulphate (NH4)2S2O8 as an oxidizing agent. This polymer was blended with different weight ratios (0%, 10%, 15%, 25%, 35%, 45%, 50%) of poly(ethylene oxide) (PEO) to produce nano conducting polyblend POT-DPSA/PEO, prepared by the spin coating method, and deposited on a glass substrate. The surface morphology was studied by scanning electron microscope. The optical properties of a prepared film was studied from the absorbance spectra at wavelengths 300–1100 nm. The analysis of optical measurement data shows the direct transition with the energy gap decreasing from 2.80 eV to 2.25 eV, as the content of PEO increases from 0% to 50%.
References
<li>P.-C. Wang, et al. Transparent electrodes based on conducting polymers for display applications. Displays 34 (4), 301 (2013).
<a href="https://doi.org/10.1016/j.displa.2013.05.003">https://doi.org/10.1016/j.displa.2013.05.003</a>
</li>
<li>M. Jaymand. Recent progress in chemical modification of polyaniline. Progress in Polymer Science 38 (9), 1287 (2013).
<a href="https://doi.org/10.1016/j.progpolymsci.2013.05.015">https://doi.org/10.1016/j.progpolymsci.2013.05.015</a>
</li>
<li>X. Guo, M. Baumgarten, K. M?ullen. Designing п-conjugated polymers for organic electronics. Progress in Polymer Science 38 (12), 1832 (2013).
<a href="https://doi.org/10.1016/j.progpolymsci.2013.09.005">https://doi.org/10.1016/j.progpolymsci.2013.09.005</a>
</li>
<li>Y. Zhao, S. Si, C. Liao. A single flow zinc//polyaniline suspension rechargeable battery. J. Power Sources 241, 449 (2013).
<a href="https://doi.org/10.1016/j.jpowsour.2013.04.095">https://doi.org/10.1016/j.jpowsour.2013.04.095</a>
</li>
<li>L. Wang et al. Graphene sheets, polyaniline and AuNPs based DNA sensor for electrochemical determination of BCR/ABL fusion gene with functional hairpin probe. Biosensors and Bioelectronics 51, 201 (2014).
<a href="https://doi.org/10.1016/j.bios.2013.07.049">https://doi.org/10.1016/j.bios.2013.07.049</a>
</li>
<li>G. Gupta et al. Polyaniline-lignosulfonate/epoxy coating for corrosion protection of AA2024-T3. Corrosion Science 67, 256 (2013).
<a href="https://doi.org/10.1016/j.corsci.2012.10.022">https://doi.org/10.1016/j.corsci.2012.10.022</a>
</li>
<li>A.R. Elkais et al. The influence of thin benzoate-doped polyaniline coatings on corrosion protection of mild steel in different environments. Progress in Organic Coatings 76(4), 670 (2013).
<a href="https://doi.org/10.1016/j.porgcoat.2012.12.008">https://doi.org/10.1016/j.porgcoat.2012.12.008</a>
</li>
<li>P.L. Burn, S.C. Lo, I.D. Samuel. The development of light-emitting dendrimers for displays. Advanced Materials 19 (13), 1675 (2007).
<a href="https://doi.org/10.1002/adma.200601592">https://doi.org/10.1002/adma.200601592</a>
</li>
<li>S. Nam et al. Solvent-free solution processed passivation layer for improved long-term stability of organic field-effect transistors. J. Mater. Chem. 21 (3), 775 (2011).
<a href="https://doi.org/10.1039/C0JM00898B">https://doi.org/10.1039/C0JM00898B</a>
</li>
<li> K. Ziadan, H. Hussein, K. Ajeel. Study of the electrical characteristics of poly (o-toluidine) and application in solar cell. Energy Procedia 18, 157 (2012).
<a href="https://doi.org/10.1016/j.egypro.2012.05.027">https://doi.org/10.1016/j.egypro.2012.05.027</a>
</li>
<li> E.L.Williams et al. Conducting polymer and hydrogenated amorphous silicon hybrid solar cells. Appl. Phys. Lett. 87 (22), 223504 (2005).
<a href="https://doi.org/10.1063/1.2136409">https://doi.org/10.1063/1.2136409</a>
</li>
<li> P.-J. Alet et al. Hybrid solar cells based on thin-film silicon and P3HT-A first step towards nano-structured devices. Europ. Phys. J. Appl. Phys. 36 (3), 231 (2006).
<a href="https://doi.org/10.1051/epjap:2006145">https://doi.org/10.1051/epjap:2006145</a>
</li>
<li> N. Gospodinova, L. Terlemezyan. Conducting polymers prepared by oxidative polymerization: polyaniline. Progress in Polymer Science 23 (8), 1443 (1998).
<a href="https://doi.org/10.1016/S0079-6700(98)00008-2">https://doi.org/10.1016/S0079-6700(98)00008-2</a>
</li>
<li> K. Gurunathan et al. Electrochemically synthesised conducting polymeric materials for applications towards technology in electronics, optoelectronics and energy storage devices. Mater. Chem. Phys. 61 (3), 173 (1999).
<a href="https://doi.org/10.1016/S0254-0584(99)00081-4">https://doi.org/10.1016/S0254-0584(99)00081-4</a>
</li>
<li> A.J. Heeger. Polyaniline with surfactant counterions: Conducting polymer materials which are processible in the conducting form. Synthetic Metals 57 (1), 3471 (1993).
<a href="https://doi.org/10.1016/0379-6779(93)90462-6">https://doi.org/10.1016/0379-6779(93)90462-6</a>
</li>
<li> Y. Kang, M.-H. Lee, S.B. Rhee. Electrochemical properties of polyaniline doped with poly (styrenesulfonic acid). Synthetic Metals 52 (3), 319 (1992).
<a href="https://doi.org/10.1016/0379-6779(92)90031-D">https://doi.org/10.1016/0379-6779(92)90031-D</a>
</li>
<li> A. Elmansouri et al. Spectroscopic characterization of electrodeposited poly(o-toluidine) thin films and electrical properties of ITO/poly(o-toluidine)/aluminum schottky diodes. Active and Passive Electronic Components 2007, 7 (2007).
<a href="https://doi.org/10.1155/2007/17846">https://doi.org/10.1155/2007/17846</a>
</li>
<li> M.Z. Kareema, F. Hussein. K.I. Ajeel. Study of the electrical characteristics of poly(o-toluidine) doped with paratoluene sulphonic acid/n-type silicon heterojunction solar cells. In: 2nd international conference on solar energy materials (solar Asia 2013) 22–24 Ague, Universiti Malaya, 50603, Kuala Lumpur. Malaysia 250 (2013).
</li>
<li> M. Kareema, W.T.S. Ziadan. Study of the electrical characteristics of polyaniline prepared electrochemical polymerization (Energy procedia, 2012).
</li>
<li> W. Pan, Q. Zhang, Y. Chen. Characterization of PAN/PANI-DBSA blend nanofibers produced by electrospinning method. Optoelectron Adv. Mater Rapid Commun. 4, 2118 (2010).
</li>
<li> T.J. Alwan, K.M. Ziadan, K.K. Kadhum. Alignment Nanofibers Conducting Polymer (PAni. CSA/PEO) Preparation by Electrospinning Technique. Intern. Review Phys. (IREPHY) 7(2), 185 (2013).
</li>
<li> J.M. Deitzel et al. The effect of processing variables on the morphology of electrospun nanofibers and textiles. Polymer 42 (1), 261 (2001).
<a href="https://doi.org/10.1016/S0032-3861(00)00250-0">https://doi.org/10.1016/S0032-3861(00)00250-0</a>
</li>
<li> A. Elmansouri et al. Spectroscopic characterization of electrodeposited poly (o-toluidine) thin films and electrical properties of ITO/poly (o-toluidine)/aluminum Schottky diodes (Active and Passive Electronic Components, 2007).
<a href="https://doi.org/10.1155/2007/17846">https://doi.org/10.1155/2007/17846</a>
</li>
<li> Y. Ramadin et al. Optical properties of epoxy-glass mi- croballoons composite. Optical Materials 5 (1–2), 69 (1996).
<a href="https://doi.org/10.1016/0925-3467(95)00033-X">https://doi.org/10.1016/0925-3467(95)00033-X</a>
</li>
<li> F. Al-Eithan, M. Al-Edani, A. Abass. Optical Band of Triglycine Selenate (TGSe) Single Crystals. Phys. Status Solidi A 103(2), 571 (1987).
<a href="https://doi.org/10.1002/pssa.2211030230">https://doi.org/10.1002/pssa.2211030230</a>
</li>
<li> M.R. Safenaz, M. Sheikha. Synthesis and electrical properties of polyaniline composite with silver nanoparticles (Advances in Materials Physics and Chemistry, 2012).
</li></ol>
Downloads
Published
How to Cite
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.
.png){kind=small}
