Entropy Production by the Diffusion Process in a Plane-Parallel Pore in the Case of Scatchard–Hamer Solution

D. A. Gavryushenko; O. V. Korobko; V. M. Sysoev; K. V. Cherevko

doi:10.15407/ujpe59.07.0732

Entropy Production by the Diffusion Process in a Plane-Parallel Pore in the Case of Scatchard–Hamer Solution

Authors

D. A. Gavryushenko Taras Shevchenko National University of Kyiv, Faculty of Physics
O. V. Korobko Taras Shevchenko National University of Kyiv, Faculty of Physics
V. M. Sysoev Taras Shevchenko National University of Kyiv, Faculty of Physics
K. V. Cherevko Taras Shevchenko National University of Kyiv, Faculty of Physics

DOI:

https://doi.org/10.15407/ujpe59.07.0732

Keywords:

Scatchard–Hamer solution, entropy production, facilitated diffusion

Abstract

An expression for the entropy production in the case of facilitated diffusion in a Scatchard–Hamer binary solution has been obtained. The presence of a stabilizing effect for the entropy production with respect to the concentration gradient is shown. The entropy-driven contributions to the variation of thermodynamic potentials at the mixing are demonstrated to play the dominant role for the entropy production in the system.

References

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https://doi.org/10.1021/ja01313a016

L.A. Bulavin, D.A. Gavryushenko, V.M. Sysoev, and K.V. Cherevko, Dopov. Nats. Akad. Nauk Ukr. No. 12, 70 (2012).

B.A. Wittenberg, J.B. Wittenberg, and P.R.B. Caldwell, J. Biol. Chem. 250, 9038 (1975).

V.A. Durov and E.P. Ageev, Thermodynamic Theory of Solutions (Moscow State Univ., Moscow, 1987) (in Russian).

L.A. Bulavin, D.A. Gavryushenko, O.V. Korobko, V.M. Sysoev, and K.V. Cherevko, Dopov. Nats. Akad. Nauk Ukr. No. 5, 76 (2014).

https://doi.org/10.15407/dopovidi2014.05.076

B.A. Wittenberg and J.B. Wittenberg, Annu. Rev. Physiol. 51, 857 (1989).

https://doi.org/10.1146/annurev.ph.51.030189.004233

D.A. Gavryushenko, O.V. Korobko, V.M. Sysoev, and K.V. Cherevko, Ukr. Fiz. Zh. 53, 989 (2013).

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Published

2018-10-24

How to Cite

Gavryushenko, D. A., Korobko, O. V., Sysoev, V. M., & Cherevko, K. V. (2018). Entropy Production by the Diffusion Process in a Plane-Parallel Pore in the Case of Scatchard–Hamer Solution. Ukrainian Journal of Physics, 59(7), 732. https://doi.org/10.15407/ujpe59.07.0732

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Issue

Vol. 59 No. 7 (2014)

Section

General problems of theoretical physics

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