Influence of Radiation on the Phase Transition Temperature in Liquids

  • L. A. Bulavin Taras Shevchenko National University of Kyiv, Institute for Safety Problems of Nuclear Power Plants, Nat. Acad. of Sci. of Ukraine
  • D. A. Gavryushenko Taras Shevchenko National University of Kyiv
  • K. V. Taradii Taras Shevchenko National University of Kyiv
  • N. A. Atamas’ Taras Shevchenko National University of Kyiv
  • V. M. Sysoev Taras Shevchenko National University of Kyiv
Keywords: radiation, phase transition, multicomponent system


The influence of radiation on the thermodynamic properties of liquid systems that are governed by the radiation-induced change in the chemical potentials of the liquid and its components has been studied. The irradiation of coexisting phases in the stationary state is shown to result in a shift of the phase transition point parameters. The temperature shift of the first-order phase transition under the influence of radiation is evaluated with regard for both the entropy and interaction factors in the chemical potential of the system.


I.G. Dragani?c, Radiolysis of water: a look at its origin and occurrence in the nature, Radiation Phys. Chem. 72, 181 (2005)

T. P?alfi, L. Wojn?arovits, and E. Tak?acs, Calculated and measured transient product yields in pulse ra-diolysis of aqueous solutions: Concentration depen-dence, Radiation Phys. Chem. 79, 1154 (2010)

K.O. Trachenko, M.T. Dove, and E.K. Salje, Atom-istic modelling of radiation damage in zircon, J. Phys.:Condens. Matter 13, 1947 (2001)

K.O. Trachenko, M.T. Dove, T. Geisler, I. Todorov, and B. Smith, Radiation damage effects and percolation the-ory, J. Phys.: Condens. Matter 16, S2623 (2004)

K. Trachenko, E. Zarkadoula, I. Todorov, M. Dove, D. Dunstan, and K. Nordlund, Modeling high-energy ra-diation damage in nuclear and fusion applications, Nucl. Instr. Meth. Phys. Rev. B 277, 6 (2012)

E. Zarkadoula et al., The nature of high-energy radiation damage in iron, J. Phys.: Condens. Matter 25, 125402 (2013)

L. Malerba et al., Ab initio calculations and interatomic potentials for iron and iron alloys: Achievements within the Perfect Project, J. Nucl. Mater. 406, 7 (2010)

I.A. Shkrob, T.W. Marin, S.D. Chemerisov, and J.F. Wi-shar, Radiation induced redox reactions and fragmenta-tion of constituent ions in ionic liquids. 1. Anions, J. Phys. Chem. B 115, 3872 (2011)

K. Trachenko et al., Radiation damage in the bulk and at the surface, Mol. Simulat. 31, 355 (2005)

V.V. Brazhkin et al., “Liquid-gas” transition in the super-critical region: Fundamental changes in the particle dy-namics, Phys. Rev. Lett. 111(14), 145901 (2011)

A.V. Chalyi, L.A. Bulavin, V.F. Chekhun et al., Univer-sality classes and critical phenomena in confined liquid systems, Condens. Matter Phys. 16, 23008 (2013)

A.V. Chalyi and E.V. Zaitseva, A kinetic model of synaptic transmission on intercell interaction, Ukr. J. Phys. 54, 366 (2009).

A.V. Chalyi and E.V. Zaitseva, Strange attractor in kinetic model of synaptic transmission, J. Phys. Studies 11, 322 (2007).

V.M. Novikov, V.V. Ignat’ev, V.I. Fedulov, and V.N. Che-rednikov, Liquid Salt NEI: Perspectives and Problems (En-ergoatomizdat, Moscow, 1990) (in Russian) [ISBN: 5-283-03791-6

M. Rosenthal, R. Briggs, and P. Haubenreich, Molten-salt reactor program. Semiannual progress report for period ending August 31, 1971, preprint ORNL-4728 (1972).

S.A. Bznuni, V.S. Barashenkov, and V.M. Zhamkochyan, Perspective two-reactor electronuclear systems, Fiz. Elem. Chast. At. Yadra 34 977 (2003).

A.K. Pikaev and V.I. Spitsyn, Modern Radiation Chem-istry: Radiolysis of Gases and Fluids (Nauka, Moscow, 1986) (in Russian).

D.A. Gavryushenko, The influence of irradiation on phase transition properies i n fluid systems, Dopov. Nats. Akad. Nauk Ukr., No. 8, 83 (2013).

D.N. Zubarev, Mechanics (Consultants Bureau, New York, 1974).

M. Kac, Probability and Related Topics in Physical Sci-ences (Amer. Math. Soc., New York, 1959).

I. Prigogine, Mechanics (Interscience, New York, 1962).

I. Prigogine, Introduction to Thermodynamics of Irre-versible Processes (Interscience, New York, 1962).

S.R. de Groot and P. Mazur, Nonequilibrium Thermody-namics (North-Holland, Amsterdam, 1963).

L.A. Bulavin, D.A. Gavryushenko, and V.M. Sysoev, Molecular Physics (Znannya, Kyiv, 2006) (in Ukrainian).

D. Kondepudi and I. Prigogine, Modern Thermodynamics: from Heat Engines to Dissipative Structures (Wiley, New York, 2014).

P.A. Selishchev, Self Organization in Radiation Physics (Aspekt-Poligraf, Kiev, 2004) (in Russian).

M.P. Kozlovskii and R.V. Romanik, Influence of an ex-ternal field on the critical behavior of the 3D Ising-like model, J. Molec. Liq. 167, 14 (2012)

M.P. Kozlovskii, Recurrence relations for the three-dimensional Ising-like model in the external field, Condens. Matter. Phys. 8, 473 (2005).

K. Trachenko, J.M. Pruneda, and E. Artacho, How the nature of the chemical bond governs resistance to amor-phization by radiation damage, Phys. Rev. B 71, 184104 (2005)

M. Chiapetto, C.S. Becquart, C. Domain, and L. Malerba, Nanostructure evolution under irradiation of Fe(C)MnNi model alloys for reactor pressure vessel steels, Nucl. Instr. Methods Phys. Res. B 352, 56 (2015)

V.A. Durov and E.P. Ageev, Thermodynamical Theory of Solutions of Nonelectrolytes (Moscow State Univ., Moscow, 1987) (in Russian).

V.M. Sysoev and S.A. Terletskii, On the influence of the third component on the mutual solvability of two fluids, Zh. Fiz. Khim. 58, 370 (1984).

N.A. Atamas, L.A. Bulavin, V.I. Kovalchuk, and A.M. Mayko, Influence of radiation on the local structure in a NaCl aqueous solution, Ukr. J. Phys. 60, 422 (2015).

T. Schlick, Molecular Modeling and Simulation: An Inter-disciplinary Guide (Springer, New York, 2002).

M.P. Allen and D.Y. Tildesley, Computer Simulation of Liquids (Clarendon Press, Oxford, 2010).

How to Cite
Bulavin, L., Gavryushenko, D., Taradii, K., Atamas’, N., & Sysoev, V. (2019). Influence of Radiation on the Phase Transition Temperature in Liquids. Ukrainian Journal of Physics, 61(9), 819.
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