High-Pressure Reorganization of the Fractal Pore Structure in Detonation Nanodiamond Powders
DOI:
https://doi.org/10.15407/ujpe66.7.635Keywords:
detonation nanodiamonds, porosity, fractal clusters, high pressure, small-angle neutron scattering, X-ray diffraction analysisAbstract
Diamond nanoparticles have significant prospects for technological applications, so their manufacture and subsequent disaggregation are a challenging task. In this paper, the porous structure of aggregates in detonation nanodiamond powders has been analyzed using small-angle neutron scattering. The influence of high pressure allowed the contributions to the small-angle scattering from micro- and nano-sized pores to be separated. The type of fractal clusters formed by nanopores was determined. The possibility of a partial mechanical disaggregation of nanodiamond particles at a pressure of 1.5 GPa is confirmed.
References
O.A. Shenderova, V.V. Zhirnov, D.W. Brenner. Carbon nanostructures. Crit. Rev. Solid State Mater. Sci. 27, 227 (2002). https://doi.org/10.1080/10408430208500497
O.V. Tomchuk, M.V. Avdeev, A.T. Dideikin et al. Revealing the structure of composite nanodiamond-graphene oxide aqueous dispersions by small-angle scattering. Diamond Relat. Mater. 103, 107670 (2020). https://doi.org/10.1016/j.diamond.2019.107670
E. Osawa. Monodisperse single nanodiamond particulates. Pure Appl. Chem. 80, 1365 (2008). https://doi.org/10.1351/pac200880071365
V.N. Mochalin, O. Shenderova, D. Ho et al. The properties and applications of nanodiamonds. Nat. Nanotechnol. 7, 11 (2012). https://doi.org/10.1038/nnano.2011.209
O. Tomchuk, V. Ryukhtin, O. Ivankov et al. SANS analysis of aqueous dispersions of Eu- and Gd-grafted nanodiamond particles. Fuller. Nanotub. Carbon Nanostr. 28, 272 (2020). https://doi.org/10.1080/1536383X.2019.1697686
O.V. Tomchuk, L.A. Bulavin, V.L. Aksenov et al. Small-angle scattering in structural research of nanodiamond dispersions. In: Modern Problems of the Physics of Liquid Systems. Selected Reviews from the 8th International Conference "Physics of Liquid Matter: Modern Problems", May 18-22, 2018, Kyiv, Ukraine. Edited by L.A. Bulavin, L. Xu (Springer, 2019), p. 201.
https://doi.org/10.1007/978-3-030-21755-6_8
A. Kruger, F. Kataoka, M. Ozawa et al. Unusually tight aggregation in detonation nanodiamond: Identifi cation and disintegration. Carbon 43, 1722 (2005).
https://doi.org/10.1016/j.carbon.2005.02.020
A.T. Dideikin, A.E. Aleksenskii, M.V. Baidakova et al. Rehybridization of carbon on facets of detonation diamond nanocrystals and forming hydrosols of individual particles. Carbon 122, 737 (2017).
https://doi.org/10.1016/j.carbon.2017.07.013
M.V. Avdeev, V.L. Aksenov, L. Rosta. Pressure induced changes in fractal structure of detonation nanodiamond
powder by small-angle neutron scattering. Diamond Relat. Mater. 16, 2050 (2007).
https://doi.org/10.1016/j.diamond.2007.07.023
O.A. Kyzyma, A.V. Tomchuk, M.V. Avdeev et al. Structural researches of carbonic fluid nanosystems. Ukr. J. Phys. 60, 835 (2015).
https://doi.org/10.15407/ujpe60.09.0835
B.B. Mandelbrot, The Fractal Geometry of Nature (Freeman, 1982).
O.V. Tomchuk. The concept of fractals in the structural analysis of nanosystems: A retrospective look and prospects. Ukr. J. Phys. 65, 703 (2020).
https://doi.org/10.15407/ujpe65.8.709
A.I. Kuklin, A.V. Rogachev, D.V. Soloviov et al., Neutronographic investigations of supramolecular structures on upgraded small-angle spectrometer YuMO. J. Phys.: Conf. Ser. 848, 012010 (2017).
https://doi.org/10.1088/1742-6596/848/1/012010
P. Scardi, M. Leoni. Diff raction line profi les from polydisperse crystalline systems. Acta Crystallogr. A 57, 604 (2001).
https://doi.org/10.1107/S0108767301008881
O.V. Tomchuk, L.A. Bulavin, V.L. Aksenov et al. Small-angle scattering from polydisperse particles with a diffusive surface. J. Appl. Cryst. 47, 642 (2014).
https://doi.org/10.1107/S1600576714001216
G. Beaucage. Approximations leading to a unified exponential/power-law approach to small-angle scattering. J. Appl. Cryst. 28, 717 (1995).
https://doi.org/10.1107/S0021889895005292
M.V. Avdeev, N.N. Rozhkova, V.L. Aksenov et al. Aggregate structure in concentrated liquid dispersions of ultrananocrystalline diamond by small-angle neutron scattering. J. Phys. Chem. C 113, 9473 (2009).
https://doi.org/10.1021/jp900424p
O.V. Tomchuk, M.V. Avdeev, A.E. Aleksenskii et al. Sol-gel transition in nanodiamond aqueous dispersions by small-angle scattering. J. Phys. Chem. C 123, 18028 (2019).
https://doi.org/10.1021/acs.jpcc.9b03175
M.V. Avdeev, V.L. Aksenov, O.V. Tomchuk et al. The spatial diamond-graphite transition in detonation nanodiamond as revealed by small-angle neutron scattering. J.Phys.: Cond. Matt. 25, 445001 (2013). https://doi.org/10.1088/0953-8984/25/44/445001
C.M. Sorensen. Light scattering by fractal aggregates: A review. Aerosol Sci. Technol. 35, 648 (2001). https://doi.org/10.1080/02786820117868
O.V. Tomchuk. Some aspects of small-angle scattering by fractal chains. AIP Conf. Proc. 2163, 020006 (2019). https://doi.org/10.1063/1.5130085
O.V. Tomchuk, M.V. Avdeev, L.A. Bulavin. About the size cut-off effect on small-angle scattering by stochastic mass fractals. J. Surf. Invest. 14, S231 (2020). https://doi.org/10.1134/S1027451020070484
O.V. Tomchuk, M.V. Avdeev, V.L. Aksenov et al. Temperature-dependent fractal structure of particle clusters in aqueous ferrofluids by small-angle scattering. Colloids Surf. A 613, 126090 (2021). https://doi.org/10.1016/j.colsurfa.2020.126090
T. Freltoft, J.K. Kjems, S.K. Sinha. Power-law correlations and finite-size effects in silica particle aggregates studied by small-angle neutron scattering. Phys. Rev. B 33, 269 (1986). https://doi.org/10.1103/PhysRevB.33.269
Downloads
Published
How to Cite
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.
.png){kind=small}
