Випромінювання у ближньому та середньому інфрачервоному діапазоні стекол Ga2S3–GeS2–Sb2S3: Er, Nd

Автор(и)

  • V.V. Halyan Department of Experimental Physics, Information and Education Technologies, Lesya Ukrainka Volyn National University
  • A.H. Kevshyn Department of Experimental Physics, Information and Education Technologies, Lesya Ukrainka Volyn National University
  • І.А. Ivashchenko Faculty of Chemical Engineering and Technology, Cracow University of Technology
  • Т.К. Yatsyniuk Department of Experimental Physics, Information and Education Technologies, Lesya Ukrainka Volyn National University
  • B.A. Tataryn Department of Chemistry and Technology, Lesya Ukrainka Volyn National University
  • М.А. Skoryk G.V. Kurdyumov Institute for Metal Physics, Nat. Acad. of Sci. of Ukraine
  • О.О. Lebed National University of Water and Environmental Engineering
  • V.O. Yukhymchuk V. Lashkaryov Institute of Semiconductor Physics, Nat. Acad. of Sci.

DOI:

https://doi.org/10.15407/ujpe70.1.48

Ключові слова:

халькогенiднi стекла, система Ga2S3 – GeS2–Sb2S3, рiдкiсноземельнi метали, оптичне поглинання, фотолюмiнесценцiя, IЧ матерiали

Анотація

Стекла 20 моль% Ga2S3 – 60 моль% GeS2 – 20 моль% Sb2S3: Er2S3 (1–4 моль%); Nd2S3 (2 моль%) отримано методом гартування. На основi дослiджень спектрiв оптичного поглинання встановлено смуги поглинання iз максимумами 655, 755, 810, 885, 980 i 1540 нм. При збудженнi фотолюмiнесценцiї випромiнюванням з λ = 805 нм у спектрi з’являються смуги з максимумами при 1070, 1350, 1540, 1700 i 2490 нм, що вiдповiдає переходам 4F3/24I11/2 (Nd3+), 4F3/24I13/2 (Nd3+), 4I13/24I15/2 (Er3+), 4I9/24I13/2 (Er3+), 4I13/24I9/2 (Nd3+) у f-оболонках обох рiдкоземельних металiв. Високi значення коефiцiєнта пропускання скляної матрицi та iнтенсивна фотолюмiнесценцiя, зумовлена Er3+ та Nd3+, роблять її придатною для розробки оптоелектронних пристроїв, якi працюють в ближньому та середньому IЧ-дiапазонах.

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Опубліковано

2025-01-18

Як цитувати

Halyan, V., Kevshyn, A., Ivashchenko І., Yatsyniuk Т., Tataryn, B., Skoryk М., Lebed О., & Yukhymchuk, V. (2025). Випромінювання у ближньому та середньому інфрачервоному діапазоні стекол Ga2S3–GeS2–Sb2S3: Er, Nd. Український фізичний журнал, 70(1), 48. https://doi.org/10.15407/ujpe70.1.48

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