Порівняльний аналіз продуктів електродугового синтезу при використанні графіту різних марок

Автор(и)

  • Ol.D. Zolotarenko Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine, Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • E.P. Rudakova Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • I.V. Zagorulko G.V. Kurdyumov Institute for Metal Physics, Nat. Acad. of Sci. of Ukraine
  • N.Y. Akhanova Kazakhstan-British Technical University, National Nanotechnology Open Laboratory (NNOL), al-Farabi Kazakh National University
  • An.D. Zolotarenko Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine, Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • D.V. Schur Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine, The Institute of Applied Physics, Nat. Acad. of Sci. of Ukraine
  • M.T. Gabdullin Kazakhstan-British Technical University
  • M. Ualkhanova National Nanotechnology Open Laboratory (NNOL), al-Farabi Kazakh National University
  • T.V. Myronenko Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • A.D. Zolotarenko Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • M.V. Chymbai Frantsevich Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • O.E. Dubrova Chuiko Institute of Surface Chemistry, Nat. Acad. of Sci. of Ukraine

DOI:

https://doi.org/10.15407/ujpe68.1.57

Ключові слова:

нанотехнологiя, вуглецевi наноструктури (ВНС), фулерени, нанокомпозити, вуглецевi нанотрубки (ВНТ), графени, плазма, електродуговий синтез, графiт марки МПГ-7, графiт марки ЕГСП

Анотація

Методом електродугового випаровування графiту марок ЕГСП та МПГ-7 в iнертному газi (Не) отримано вуглецевi наноструктури (ВНС) рiзних типiв (вуглецевi нанотрубки, фулерени та фулереноподiбнi структури). Проведено порiвняльний аналiз синтезованих характеристик ВНС. Визначено оптимальнi технологiчнi умови для синтезу ВНС з графiтових анодних електродiв нюваних марок (ЕГСП та МПГ-7). Дослiджено метод плазмохiмiчного синтезу. За допомогою скануючої та просвiчуючої електронної мiкроскопiї дослiджено структуру синтезованих вуглецевих матерiалiв i показано, що вуглецевi нанотрубки утворюються при випаровуваннi графiту марки ЕГСП навiть без використання каталiзатора. Проведено диференцiйно-термiчний, термогравiметричний та диференцiйно-термогравiметричний аналiзи, за результатами яких встановлено температури початку взаємодiї утвореної ВНС з киснем повiтря. За даними фотоспектрального аналiзу продуктiв синтезу проведено розрахунки i показано, що фулереновий компонент, отриманий випаровуванням графiту марки ЕГСП, мiстить 10–12% фулеренiв C60 i C70, що не поступається аналогiчним показникам графiту марки МПГ-7. Беручи до уваги дешевину графiту марки ЕГСП порiвняно з маркою графiту марки МПГ-7, можна стверджувати, що вуглецевi наноструктури, синтезованi з графiту марки ЕГСП, мають меншу вартiсть. Цей факт є важливим для синтезу вуглецевих наноструктур як наповнювача для сучасних композитiв. Крiм того, синтез значно дешевших фулеренiв i фулереноподiбних молекул є великою перевагою для їх вивчення та використання в сучасних матерiалах, адже сьогоднi починають створюватися новi передовi нанотехнологiї на основi фулеренiв.

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2023-03-12

Як цитувати

Zolotarenko, O., Rudakova, E., Zagorulko, I., Akhanova, N., Zolotarenko, A., Schur, D., Gabdullin, M., Ualkhanova, M., Myronenko, T., Zolotarenko, A., Chymbai, M., & Dubrova, O. (2023). Порівняльний аналіз продуктів електродугового синтезу при використанні графіту різних марок. Український фізичний журнал, 68(1), 57. https://doi.org/10.15407/ujpe68.1.57

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