Polarization and Pyroelectric Coefficients of Antiferrodistortive Boundaries: SrTiO3 as an Example
DOI:
https://doi.org/10.15407/ujpe57.12.1223Keywords:
-Abstract
The spatial distributions and the temperature dependences of a local polarization and the pyroelectric coefficient in a vicinity of antiferrodistortive boundaries in SrTiO3 at temperatures lower than that of the antiferrodistortive structural phase transition (≈105 K) have been studied analytically and numerically in the framework of the Landau–Ginsburg–Devonshire theory. The polarization in the near-wall region is supposed to emerge as a result of the flexoelectric field and the rotostriction.
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