Theoretical and Experimental Study of Spectroscopic Characteristics of Aromatic Amino Acids

M. I. Myhovich; V. A. Kelman

doi:10.15407/ujpe59.06.0581

Theoretical and Experimental Study of Spectroscopic Characteristics of Aromatic Amino Acids

Authors

M. I. Myhovich Institute of Electron Physics, Nat. Acad. of Sci. of Ukraine
V. A. Kelman Institute of Electron Physics, Nat. Acad. of Sci. of Ukraine

DOI:

https://doi.org/10.15407/ujpe59.06.0581

Keywords:

aromatic amino acids, photoluminescence, absorption spectra, quantum transitions, HOMO (highest occupied molecular orbital), LUMO (lowest unoccupied molecular orbital), charge distribution

Abstract

Photoluminescence spectra of aromatic amino acids, which are prepared in the form of microcrystalline powders and their aqueous solutions and are excited by laser radiation, are studied. Luminescence spectral regions and the maxima of luminescence intensity are determined. The spectral dependences of the molar extinction coefficients are measured for the aqueous solutions of amino acids. The electronic absorption spectra of aromatic amino acids and the charge distribution in the corresponding molecules are calculated, by using the quantum-chemical Hartree–Fock method with the application of the semiempirical PM3 and ZINDO/S approximations. The electronic absorption spectra are analyzed.

References

S. Levchenko, V. Yashchuk, V. Kudrya, V. Mel'nyk, and V. Vorobyov, Visn. Kyiv. Univ. Ser. Fiz., No. 12, 19 (2011).

T.A. Romanova and P.V. Avramov, Biomed. Khim. 50, 56 (2004).

V.M. Kravchenko, Yu.P. Rud, L.P. Buchatski, V.I. Mel'nik, K.Yu. Mogylchak, S.P. Ladan, and V.M. Yashchuk, Ukr. J. Phys. 57, 183 (2012).

R.Sh. Zatrudina and E.P. Kon'kova, Khim. Fiz. Mezoskop. 13, 577 (2011).

P.O. Kondratenko, Yu.M. Lopatkin, and T.M. Sakun, Zh. Nano-Elektron. Fiz. 3, No. 3, 127 (2011).

Ya.O. Prostota, O.D. Kachkovskyi, O.V. Kropachev, M.Yu. Losytskyi, S.S. Tarnavskyi, and S.M. Yarmolyuk, Ukr. Bioorg. Acta 1, 32 (2007).

Yu.A. Vladimirov and E.A. Burshtein, Biofizika 5, 385 (1960).

J.R. Albani, J. Fluoresc, 17, 406 (2007).

https://doi.org/10.1007/s10895-007-0183-3

P. Held, BioTek. Application note. Rev. 4/18/03.

A.P. Osysko and P.L. Mu’ı˜no, J. Biophys. Chem. 2, 316 (2011).

https://doi.org/10.4236/jbpc.2011.23036

D.E.Groshev, V.N. Lisitsyn, V.K. Makukha, Yu.P. Meshalkin, and P.A. Rudenko, in Abstracts of the 13th Int. Conference on Coherent and Nonlinear Optics (Minsk, 1988), p. 149 (in Russian).

V.S. Gorelik, Izv. Akad. Nauk SSSR Ser. Fiz. 53, 1791 (1989).

M.E. Solovev and M.M. Solovev, Computer chemistry (SOLON-Press, Moscow, 2005) (in Russian).

M.S. Kondrat'ev, A.A. Samchenko, V.M. Komarov, and A.V. Kabanov, in Proceedings of the 12th Int. Conference "Mathematics, Computer, Education" (Regul. Khaot. Din., Izhevsk, 2005), p. 899 (in Russian).

N. Godzhaev, I. Alieva, and S. Demukhamedova, J. Qafqaz Univ. 17, 86 (2006).

J.T. Lopez Navarrete, J. Casado, V. Hernandez, and F.J Ramirez, Theor. Chem. Account. 98, 5 (1997).

https://doi.org/10.1007/s002140050272

E.P. Kon'kova and R.Sh. Zatrudina, Khim. Fiz. Vestn. Volg. Gos. Univ. Ser. 1 13, 94 (2010).

E.P. Kon'kova and R.Sh. Zatrudina, Vestn. SanktPeterburg. Gos. Univ. Ser. 4, 4, 145 (2011).

N. Galikova, M. Kelminskas, A. Gruodis, and L.M. Balevichius, Computer Modelling and New Technologies 15, No. 1, 19 (2011).

D.O. Mel'nyk and O.V.Shyichuk, Fiz. Khim. Tverd. Tila 3, 346 (2002).

R.Yu. Barakov, T.V.Solodovnik, B.P. Minaev, V.O. Minaeva, V.M. Prokopenko, and Yu.M. Kurylenko, Visn. Cherkask. Univ. Ser. Khim. Nauky 174, 80 (2010).

Downloads

Published

2018-10-23

How to Cite

Myhovich, M. I., & Kelman, V. A. (2018). Theoretical and Experimental Study of Spectroscopic Characteristics of Aromatic Amino Acids. Ukrainian Journal of Physics, 59(6), 581. https://doi.org/10.15407/ujpe59.06.0581

Download Citation

Issue

Vol. 59 No. 6 (2014)

Section

License

Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine

The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:

1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.

2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.

3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.

4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.

5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.

6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.