Anomalous Negative Thermal Expansion in a Condensed Heterogeneous Lyophobic System

Ya. G. Grosu; V. A. Eroshenko; O. V. Ievtushenko; J.-M. Nedelec; J.-P. E. Grolier

doi:10.15407/ujpe59.01.0069

Anomalous Negative Thermal Expansion in a Condensed Heterogeneous Lyophobic System

Authors

Ya. G. Grosu National Technical University of Ukraine “Kyiv Polytechnical Institute”. Laboratory of Thermo-molecular Energetics
V. A. Eroshenko National Technical University of Ukraine “Kyiv Polytechnical Institute”. Laboratory of Thermo-molecular Energetics
O. V. Ievtushenko National Technical University of Ukraine “Kyiv Polytechnical Institute”. Laboratory of Thermo-molecular Energetics, Clermont University, ENSCCF, Institute of Chemistry of Clermont-Ferrand, CNRS, UMR 6296, ICCF
J.-M. Nedelec Clermont University, ENSCCF, Institute of Chemistry of Clermont-Ferrand, CNRS, UMR 6296, ICCF
J.-P. E. Grolier Clermont University, ENSCCF, Institute of Chemistry of Clermont-Ferrand, CNRS, UMR 6296, ICCF

DOI:

https://doi.org/10.15407/ujpe59.01.0069

Keywords:

phase interface, porous body, PV-isotherm, intrusion/extrusion, simulation, experiment

Abstract

A reduction in the volume of a heterogeneous lyophobic system (HLS) at the temperature growth (the so-called negative thermal expansion, NTE) is experimentally observed. For the investigated HLS “silicalite-1 + water”, the NTE eﬀect is shown to exceed the corresponding values observed for other known materials by more than an order of magnitude. The physical principles of this phenomenon are explained, and a mathematical model for its description is proposed.

References

C.V. Raman and T.M.K. Nedungadi, Nature 145, 147 (1940).

V.A. Eroshenko, Dokl. Akad. Nauk Ukr. SSR Ser. A, No. 10, 79 (1990).

V. Korthuis, N. Khosrovani, A.W. Sleight, N. Roberts, R. Dupree, and W.W. Warren, Chem. Mater. 7, 412 (1995).

P. Tschaufeser and S.C. Parker, J. Phys. Chem. 99, 10609 (1995).

J.S.O. Evans, T.A. Mary, T. Vogt, M.A. Subramanian, and A.W. Sleight, Chem. Mater. 8, 2809 (1996).

J.S.O. Evans, J. Chem. Soc. Dalton Trans. 19, 3317 (1999).

G.D. Barrera, J.A.O Bruno, T.H.K Barron, and N.L. Allan, J. Phys. Condens. Matter 17, 217 (2005).

V.A. Eroshenko, in Capillary Properties and Adhesion of Alloys (Naukova Dumka, Kyiv, 1987), p. 100 (in Russian).

V.A. Eroshenko, Promyshl. Teplotekhn. 14, 22 (1992).

V.A. Eroshenko and Yu.F. Lazarev, Prikl. Mech. Tekhn. Fiz. 53, 98 (2012).

V. Eroshenko, R.-C. Regis, M. Soulard, and J. Patarin, J. Amer. Chem. Soc. 123, 8129 (2001).

V. Eroshenko, R.-C. Regis, M. Soulard, and J. Patarin, C.R. Acad. Sci. Ser. B 3, 111 (2002).

L. Tzanis, M. Trzpit, M. Soulard,and J. Patarin, J. Phys. Chem. C 116, 20389 (2012).

V.A. Eroshenko, Patent France WO 01/55616 A1, F 16 F 9/00.

V.A. Eroshenko, I.I. Piatiletov, L. Coiffard, and V.P. Stoudenets, Proc. Mech. Eng. D 221, 301 (2007).

C.V. Suciu, S. Tani, and K. Miyoshi, J. Syst. Design Dynam. 4, 899 (2010).

C.V. Suciu and K. Yaguchi, Exper. Mech. Int. J. 49, 383 (2009).

F.B. Surani, X. Kong, D.B. Panchal, and Y. Qiao, Appl. Phys. Lett. 87, 163111 (2005).

V.A. Eroshenko, Patent USSR 1380357 A2, F 03 G, Bull. Izobr. N 3 (1996).

A. Laouir, L. Luo, D. Tondeur, T. Cachot, and P. Le Goff, Am. Inst. Chem. Eng. 49, 764 (2003).

V.A. Eroshenko and Ya.G. Grosu, Promyshl. Teplotekhn. 33, 73 (2011).

E.W. Washburn, Phys. Rev. 17, 273 (1921).

L. Guillemot, Ph.D. thesis (Institut National des Sciences Appliquees de Lyon, 2010).

V.A. Eroshenko and S.G. Tkachenko, Ukr. Fiz. Zh. 38, 1789 (1993).

V.S. Egorov, A.G. Portyanoi, A.P. Sorokin, V.G. Maltsev, and R.M. Voznesenskii, Patent Russia RU (11) 2138086 (13) C1 (http:// www.findpatent.ru/patent/213/2138086.html).

S.L. Randzio, Chem. Soc. Rev. 25, 383 (1996).

S.L. Randzio and J.-P.E. Grolier, Anal. Chem. 70, 2327 (1998).

S.L. Randzio, Ch. Stachowiak, and J.-P.E. Grolier, J. Chem. Thermodyn. 35, 639 (2003).

D.S. Nyce, Linear Position Sensors: Theory and Application (Wiley-Interscience, Hoboken, NJ, 2004).

B.K. Greve, K.L. Martin, P.L. Lee, P.J. Chupas, K.W. Chapman, and A.P. Wilkinson, J. Am. Chem. Soc. 132, 15496 (2010).

A. Rebello, J.J. Neumeier, Z. Gao, Y. Qi, and Y. Ma, Phys. Rev. B 86, 104303 (2012).

C.W. Li, T. Xiaoli, J.A. Munoz, J.B. Keith, S.J. Tracy, D.L. Abernathy, and B. Fultz, Phys. Rev. Lett. 107, 195504 (2011).

J.P. Attfield, Nature 480, 465 (2011).

O.V. Ievtushenko, V.A. Eroshenko, Y.G. Grosu, J.-M. Nedelec, and J-P. E. Grolier, Phys. Chem. Chem. Phys. 15, 4451 (2013).

N.L. Johnson, S. Kotz, and N. Balakrishnan, Continuous Univariate Distributions, Vol. 1 (Wiley, New York, 1994).

T.G. Plachenov and S.D. Kolosentsev, Porosimetry (Khimiya, Leningrad, 1988) (in Russian).

V.A. Eroshenko and A.Yu. Fadeev, Ross. Khim. Zh. 40, 92 (1996).

L. Coiffard, and V. Eroshenko, J. Colloid Interface Sci. 300, 92 (2006).

NIST Chemistry Web Book http://webbook.nist.gov/chemistry/.

R.C. Tolman, J. Chem. Phys. 17, 333 (1949).

Downloads

Published

2018-10-18

How to Cite

Grosu, Y. G., Eroshenko, V. A., Ievtushenko, O. V., Nedelec, J.-M., & Grolier, J.-P. E. (2018). Anomalous Negative Thermal Expansion in a Condensed Heterogeneous Lyophobic System. Ukrainian Journal of Physics, 59(1), 69. https://doi.org/10.15407/ujpe59.01.0069

Download Citation

Issue

Vol. 59 No. 1 (2014)

Section

Nanosystems

License

Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine

The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:

1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.

2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.

3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.

4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.

5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.

6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.