Influence of a Cold Plastic Deformation on the Electrical Resistivity of CrMnFeCoNi High-Entropy Alloy
DOI:
https://doi.org/10.15407/ujpe62.05.0413Keywords:
high-entropy alloy, electrical resistivity, K-state, plastic deformation, structureAbstract
The influence of a cold rolling deformation on the electrical transport properties of CrMnFeCoNi high-entropy alloy (HEA) has been studied. It is shown that the growth of the strain E at rolling gives rise to a decrease of the alloy electrical resistivity p and an increase of the temperature coefficient of resistance a. The X-ray diffraction study did not reveal any phase changes at that. Such dependences of p and a on E differ from the behavior of those parameters in the majority of ordinary metal alloys. The temperature dependence of the electrical resistance of deformed samples at their heating is found to have an abnormal S-like shape. Using the positions of such S-anomalies obtained at different heating rates, the activation energy Ea of the process responsible for the appearance of this anomaly is determined with the help of the Kissinger method. The form of the dependence p(T) and the value of Ea give us ground to connect the specific features in the behavior of p in deformed specimens with the existence of a “K-state” in the examined HEA, which emerges in some deformed alloys based on transition metals. Possible thermodynamic reasons for the appearance of this state have been discussed.
References
J.-W. Yeh, S.-K. Chen, S.-J. Lin, J.-Y. Gan, T.-S. Chin, T.-T. Shun, C.-H. Tsau, S.-Y. Chang. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv. Eng. Mater. 6, 299 (2004).
https://doi.org/10.1002/adem.200300567
Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, P.K. Liaw, Z.P. Lu. Microstructures and properties of highentropy alloys. Prog. Mater. Sci. 61, 1 (2014).
https://doi.org/10.1016/j.pmatsci.2013.10.001
O.N. Senkov, G.B. Wilks, D.B. Miracle, C.P. Chuang, P.K. Liaw. Refractory high-entropy alloys. Intermetallics 18, 1758 (2010).
https://doi.org/10.1016/j.intermet.2010.05.014
C.Y. Hsu, T.S. Sheu, J.W. Yeh, S.K. Chen. Effect of iron content on wear behaviour of AlCoCrFe Mo0.5Ni highentropy alloys. Wear 268, 653 (2010).
https://doi.org/10.1016/j.wear.2009.10.013
Y.J. Zhou, Y. Zhang, Y.L. Wang, G.L. Chen. Solid solution alloy of AlCoCrFeNiTi with excellent room-temperature mechanical properties. Appl. Phys. Lett. 90, 181904 (2007).
https://doi.org/10.1063/1.2734517
Y.-F. Kao, T.D. Lee, S.K. Chen, Y.S. Chang. Electrochemical passive properties of Al CoCrFeNi (= 0, 0.25,0.50, 1.00) alloys in sulfuric acids. Corros. Sci. 52, 1026 (2010).
https://doi.org/10.1016/j.corsci.2009.11.028
M.-H. Tsai, J.W. Yeh, J.Y. Gan. Diffusion barrier properties of AlMoNbSiTaTiVZr high-entropy alloy layer between copper and silicon. Thin Solid Films 516, 5527 (2008).
https://doi.org/10.1016/j.tsf.2007.07.109
M.S. Lucas, L. Mauger, J.A. Munoz, Y. Xiao, A.O. Sheets, S.L. Semiatin, J. Horwath, Z. Turgut. Magnetic and vibrational properties of high-entropy alloys. J. Appl. Phys. 109, 07E307 (2011).
K. Zhang, Z. Fu. Effects of annealing treatment on properties of CoCrFeNiTiAl multi-component alloys. Intermetallics 28, 34(2012).
https://doi.org/10.1016/j.intermet.2012.03.059
S.-K. Chen, Y.-F. Kao. Near-constant resistivity in 4.2-360 K in a B2 Al2.08CoCrFeNi. AIP Adv. 2, 012111 (2012).
https://doi.org/10.1063/1.3679072
M.-H. Tsai. Physical properties of high entropy alloys. Entropy 15, 5338 (2013).
https://doi.org/10.3390/e15125338
H.P. Chou, Y.S. Chang, S.K. Chen, J.W. Yeh. Microstructure, thermophysical and electrical properties in Al CoCrFeNi (0 ≤ ≤ 2) high-entropy alloy. Mater. Sci. Eng. 163, 184 (2009).
https://doi.org/10.1016/j.mseb.2009.05.024
Y.-F. Kao, S.-K. Chen, T.-J. Chen, P.-C. Chu, J.-W. Yeh, S.-J. Lin. Electrical, magnetic, and Hall properties of Al CoCrFeNi high-entropy alloys. J. Alloys Compd. 509, 1607 (2011).
https://doi.org/10.1016/j.jallcom.2010.10.210
M.O. Krapivka, Yu.P. Mazur, M.P. Semen'ko, S.A. Firstov. Structureof high-entropy alloys CrMnFeCoNi and CrMnFeCoNi2Cu and thermal stability of their charge transport properties. Metallofiz. Noveish. Tekhnol. 37, 731 (2015) (in Ukrainian).
https://doi.org/10.15407/mfint.37.06.0731
H.E. Kissinger. Reaction kinetics in differential thermal analysis. Anal. Chem. 29, 1702 (1957).
https://doi.org/10.1021/ac60131a045
F. Liu, F. Sommer, C. Bos, E.J. Mittemeijer. Analysis of solid state phase transformation kinetics: Models and recipes. Int. Mat. Rev. 52, 193 (2007).
https://doi.org/10.1179/174328007X160308
F. Otto, N.L. Hanold, E.P. George. Microstructural evolution after thermomechanical processing in an equiatomic, single-phase CoCrFeMnNi high-entropy alloy with special focus on twin boundaries. Intermetallics 54, 39 (2014).
https://doi.org/10.1016/j.intermet.2014.05.014
W.H. Liu, Y. Wu, J.Y. He, T.G. Nieh, Z.P. Lu. Grain growth and the Hall–Petch relationship in a high-entropy FeCrNiCoMn alloy. Scripta Materialia 68, 526 (2013).
https://doi.org/10.1016/j.scriptamat.2012.12.002
H. Thomas. Uber widerstandslegierungen. ¨ Z. Phys. 129, 219 (1951).
https://doi.org/10.1007/BF01333398
G. Grube, H. Schlecht. Electroconductivity and phase diagrams of binary alloys. Z. Elektrochem. 44, 413 (1938).
E. Ruedl, P. Delavignette, S. Amelinckx. Electron diffraction and electron microscopic study of long- and shortrange order in Ni4Mo and of the substructure resulting from ordering. Phys. Status Solidi 28, 305 (1968).
https://doi.org/10.1002/pssb.19680280132
J.E. Spruiell, E.E. Stansbury. X-ray study of short-range order in nickel alloys containing 10.7 and 20.0 at.% molybdenum. J. Phys. Chem. 26, 811 (1965).
https://doi.org/10.1016/0022-3697(65)90256-8
D.M.C. Nicholson, R.H. Brown. Electrical resistivity of Ni0.8Mo0.2: Explanation of anomalous behavior in shortrange ordered alloys. Phys. Rev. Lett. 70, 3311 (1993).
https://doi.org/10.1103/PhysRevLett.70.3311
Yu.N. Gornostyrev, M.I. Katsnelson. Misfit stabilized embedded nanoparticles in metallic alloys. Phys. Chem. Chem. Phys. 17, 27249 (2015).
https://doi.org/10.1039/C5CP04641F
S. Lowitzer, D. K¨odderitzsch, H. Ebert, P.R. Tulip, A. Marmodoro, J.B. Staunton. An ab initio investigation of how residual resistivity can decrease when an alloy is deformed. Europhys. Lett. 92, 37009 (2010).
https://doi.org/10.1209/0295-5075/92/37009
J.-W. Yeh, S.-Y. Changb, Y.-D. Honga, S.-K. Chenc, S.-J. Lin. Anomalous decrease in X-ray diffraction intensities of Cu–Ni–Al–Co–Cr–Fe–Si alloy systems with multiprincipal elements. Mater. Chem. Phys. 103, 41 (2007).
https://doi.org/10.1016/j.matchemphys.2007.01.003
E. Nunes, J.C.C. Freitas, R.D. Pereira, A.Y. Takeuchi, C. Larica, E.C. Passamani, A.A.R. Fernandes. Phase transformation in iron/cobalt-based amorphous alloys revealed by thermal and magnetic techniques. J. Alloys Comp. 369, 131 (2004).
https://doi.org/10.1016/j.jallcom.2003.09.072
Z. Stok losa, J. Rasek, P. Kwapuli’nski, G. Haneczok, G. Badura, J. Lelatko. Nanocrystallization of amorphous alloys based on iron. Mater. Sci. Eng. C 23, 49 (2003).
K.Y. Tsai, M.H. Tsai, J.W. Yeh. Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys. Acta Mater. 61, 4887 (2013).
https://doi.org/10.1016/j.actamat.2013.04.058
C. Zhu, Z.P. Lu, T.G. Nieh. Incipient plasticity and dislocation nucleation of FeCoCrNiMn high-entropy alloy. Acta Mater. 61, 2993 (2013).
https://doi.org/10.1016/j.actamat.2013.01.059
F. Otto, Y. Yang, H. Bei, E.P. George. Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys. Acta Mater. 61, 2628 (2013).
https://doi.org/10.1016/j.actamat.2013.01.042
A. Takeuchi, A. Inoue. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater. Trans. 46, 2817 (2005).
Downloads
Published
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.
.png){kind=small}
