Comparative Analysis of the Temperature Dependence of Adiabatic Thermodynamic Coefficients of Liquid H2O, H2O2, and Ar
DOI:
https://doi.org/10.15407/ujpe70.2.99Keywords:
water, argon, hydrogen peroxide, adiabatic compressibility coefficient, sound speed, hydrogen bondsAbstract
Temperature dependences of the adiabatic thermodynamic coefficients of water, where the network of hydrogen bonds is formed under certain conditions, have been compared with the corresponding dependences for hydrogen peroxide, where hydrogen bonds do exist, but the network of hydrogen bonds does not, and for argon with no hydrogen bonds at all. In our opinion, specific temperature dependences of the indicated parameters for water are associated with the existence of a network of hydrogen bonds in water under certain conditions. This network is formed by two dynamic structures (the LWD and HDW phases) and is responsible for the hierarchy of anomalous water properties in a wide temperature interval. In addition, it has been shown that the network of hydrogen bonds substantially affects the behavior of the temperature dependence of the sound propagation speed related to the adiabatic coefficient of liquid compressibility.
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