A Change in the Chemical Potential in Liquids under the Action of Radiation and an External Field
DOI:
https://doi.org/10.15407/ujpe69.12.930Keywords:
phase transition, critical phenomena, chemical potential, spatially confined system, equilibrium thermodynamicsAbstract
The influence of the spatial confinement and radiation on the thermodynamic behavior of the equilibrium properties of liquid systems has been studied. The theory of spatially confined inhomogeneous liquids has been generalized in order to take the correlation effects in such systems into account. The obtained results allow the spatial distribution of the density in binary liquid systems subjected to the action of radiation and external fields to be calculated in a wide range of thermodynamic parameters.
References
J.W. Gibbs. Elementary Principles in Statistical Mechanics: Developed with Especial Reference to the Rational Foundations of Thermodynamics (Dover, 1960).
D.A. Gavryushenko, K.V. Taradii. Influence of radiation on physical properties of liquids. Ukr. J. Phys. 60, 763 (2015).
https://doi.org/10.15407/ujpe60.08.0764
K.V. Cherevkov, L.A. Bulavin, L.L. Jenkovszky, V.M. Sysoev, F.-S. Zhang. Evaluation of the curvature-correction term from the equation of state of nuclear matter. Phys. Rev. C 90, 017303 (2014).
https://doi.org/10.1103/PhysRevC.90.017303
D.A. Gavryushenko, O.V. Korobko, V.M. Sysoev, K.V. Cherevko. Entropy production in the diffusion of a Margules solution in a plane-parallel pore. Ukr. J. Phys. 58, 988 (2018).
https://doi.org/10.15407/ujpe58.10.0988
A.N. Vasilev, A.V. Chalyi. Cooperative operation mode of a synaptic channel. Ukr. J. Phys. 54, 1183 (2009).
A.N. Grigoriev, Yu.G. Kuzovkov, I.V. Markov, L.A. Bulavin. Particle-shape effect on thermophysical properties of model liquid systems solutions of hard spherocylinders. Ukr. J. Phys. 66, 873 (2021).
https://doi.org/10.15407/ujpe66.10.873
M.E. Fisher. Critical phenomena. In: Proc. the International School of Physics "Enrico Fermi" . Edited by M.S. Green (Academic Press, 1971).
V. Privman, M.E. Fisher. Finite-size effects at first-order transitions. J. Stat. Phys. 33, 385 (1983).
https://doi.org/10.1007/BF01009803
D.N. Zubarev, V.G. Morozov, G. Ropke. Statistical Mechanics of Nonequilibrium Processes, Vol. 1, Basic Concepts, Kinetic Theory (Akademie, 1996).
D.N. Zubarev, V.G. Morozov, G. Ropke. Statistical Mechanics of Nonequilibrium Processes, Vol. 2, Relaxation and Hydrodynamic Processes (Akademie, 1997).
A. M¨unster. Classical Thermodynamics (Wiley-Interscience, 1970).
R. Lovett, B. Baus. On the existence of free energy densities in non-uniform fluids. Physica A 181, 309 (1992).
https://doi.org/10.1016/0378-4371(92)90091-4
A.V. Chalyi, A.N. Vasil'ev. Correlation properties, critical parameters and critical light scattering in finite-size systems. J. Mol. Liq. 84, 203 (2000).
https://doi.org/10.1016/S0167-7322(99)00187-7
A.V. Chalyi, L.A. Bulavin, V.F. Chekhun, K.A. Chalyy, L.M. Chernenko, A.M. Vasilev, E.V. Zaitseva, G.V. Khrapijchyk, A.V. Siverin, M.V. Kovalenko. Universality classes and critical phenomena in confined liquid systems. Condens. Matter Phys. 16, 23008 (2013).
https://doi.org/10.5488/CMP.16.23008
H.T. Davis, L.E. Scriven. The pair and direct correlation functions of an inhomogeneous fluid. J. Chem. Phys. 69, 5215 (1978).
https://doi.org/10.1063/1.436573
D.A. Gavryushenko. The distribution of components of a binary solution in the spatially bounded system. A planar pore with asymmetric near-wall potential. Ukr. J. Phys. 53, 1161 (2008).
L.A. Bulavin, D.A. Gavryushenko, V.M. Sysoev. Spatial distribution of components of a binary mixture in a bounded system. Ukr. J. Phys. 52, 934 (2007).
Downloads
Published
How to Cite
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.