Plasmon Resonance Properties of Au, Cu and Ag Multi-layered Structures with P(VDF-TrFE)
DOI:
https://doi.org/10.15407/ujpe68.9.594Keywords:
surface plasmon resonance, biosensor, P(VDF-TrFE), thin metal films, tunable sensor, attenuated total reflectionAbstract
The theoretical modeling of the optical response of layered metal-polymer structures, which can be employed as plasmonic sensors, is carried out. The calculation of their linearly polarized light reflection is performed with the use of the well-known matrix method, which describes the electromagnetic radiation propagation through a sequence of homogeneous flat-parallel media layers. In this way, the attenuated total reflection curves of the structures containing metal films (Au, Cu, or Ag) and a polymer dielectric are obtained and analyzed. A new sensor is proposed, which will utilize the ferroelectric P(VDF-TrFE) copolymer separating metal films. This might be a perspective idea for the creation of tunable plasmonic sensors. The dependencies of the angular position of a surface plasmon resonance versus the thicknesses of structure’s layers, as well as versus the refractive index of the medium contacting to the free surface of a sensor, are considered. This makes it possible to carry out the approximate search for optimal constructive parameters of a sensor, namely, the thicknesses of metal and polymer layers, and to make conclusion about its resulting sensitivity and working range. It is found that the sensors based on a single metal film and a couple of such films separated by a polymer differ 1 ... 1.3 times in the sensitivity (single metal film demonstrates a more rapid resonant angle shift with analyte refractive index variation). It is established that the employment of Au, Cu, or Ag gives no significant changes in the sensitivity of a two-metal-layer sensor with a polymer, but the widest refractive index registration range may be expected for a Cu-based sensor.
References
B. Douzi. Protein-protein interactions: Surface plasmon resonance. Methods Mol. Biol. 1615, 257 (2017).
https://doi.org/10.1007/978-1-4939-7033-9_21
K. Narayan, S.S. Carroll. SPR Screening. In Applied Biophysics for Drug Discovery. 1st edition. Edited by D. Huddler, E.R. Zartler (John Wiley & Sons Ltd, 2017).
https://doi.org/10.1002/9781119099512.ch6
W.M.E.M.M. Daniyal, Y.W. Fen, N.A.A. Anas, N.A.S. Omar, N.S.M. Ramdzan, H.Nakajima, M.A. Mahdi. Enhancing the sensitivity of a surface plasmon resonance-based optical sensor for zinc ion detection by the modification of a gold thin film. RSC Advances 9 (71), 41729 (2019).
https://doi.org/10.1039/C9RA07368J
Y. Song, M. Sun, H. Wu, W. Zhao, Q. Wang. Temperature sensor based on surface plasmon resonance with TiO2-Au-TiO2 triple structure. Materials 15, 7766 (2022).
https://doi.org/10.3390/ma15217766
A.D. Suprun, L.V. Shmeleva. Conditions changing for the surface plasmon resonance realization in optical sensors under the temperature influence. Eur. Phys. J. Plus 137, 580 (2022).
https://doi.org/10.1140/epjp/s13360-022-02798-1
V.G. Kravets, R. Jalil, Y.-J. Kim, D. Ansell, D.E. Aznakayeva, B. Tchackray, L. Britnell, B.D. Belle, F. Withers, I.P. Radko, Z. Han, S.I. Bozhevolnyi, K.S. Novoselov, A.K. Geim, A.N. Grigorenko. Graphene-protected copper and silver plasmonics. Scientific Reports 4 (1), 5517 (2014).
https://doi.org/10.1038/srep05517
N. Andam, S. Refki, S. Hayashi, Z. Sekkat. Plasmonic mode coupling and thin film sensing in metal-insulator-metal structures. Scientific Reports 11, 15093 (2021).
https://doi.org/10.1038/s41598-021-94143-2
K. Tiwari, S. Sharma, N. Hozhabri. Hafnium dioxide as a dielectric for highly-sensitive waveguide-coupled surface plasmon resonance sensors. AIP Advances 6, 045217 (2016).
https://doi.org/10.1063/1.4948454
V.G. Kravets, P.Y. Kurioz, L.V. Poperenko. Spectral dependence of the magnetic modulation of surface plasmon polaritons in permalloy/noble metal films. J. Opt. Soc. America B 31 (8), 1836 (2014).
https://doi.org/10.1364/JOSAB.31.001836
P.H. Berning. Theory and calculations of optical thin films. In: Physics of Thin Films. Edited by G. Hass (Academic Press, 1963) [ISBN: 0125330014].
K.M. Mc Peak, S.V. Jayanti, S.J.P. Kress, S. Meyer, S. Iotti, A. Rossinelli, D.J. Norris.. Plasmonic films can easily be better: Rules and recipes. ACS Photonics 2 (3), 326 (2015).
https://doi.org/10.1021/ph5004237
J.B. Maurya, Y.K. Prajapati. Influence of dielectric coating on performance of surface plasmon resonance sensor. Plasmonics 12 (4), 1121 (2016).
https://doi.org/10.1007/s11468-016-0366-3
L.V. Poperenko, A.L. Yampolskiy, O.V. Makarenko, O.I. Zavalistyi. Optimization of optical parameters of metal-dielectric heterostructures for plasmonic sensors formation. Metallofiz. Noveishie Tekhnol. 41 (6), 751 (2019).
Downloads
Published
How to Cite
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.