Temperature and Pressure Effect on the Thermodynamics Coefficient (∂V/∂T)p of Water

Authors

  • L.A. Bulavin Taras Shevchenko National University of Kyiv, Faculty of Physics
  • Ye.G. Rudnikov Taras Shevchenko National University of Kyiv, Faculty of Physics, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”

DOI:

https://doi.org/10.15407/ujpe68.2.122

Keywords:

water, argon, isobaric expansion coefficient, liquid-vapor coexistence curve, liquid-solid coexistence curve, hydrogen bonds

Abstract

On the basis of literature data, the temperature and pressure dependences of the thermodynamic coefficient (∂V/∂T)P for liquid water have been calculated and analyzed. The obtained results are compared with the relevant data for argon. Taking the principle of corresponding states into account, the existence of a region, where the thermodynamic similarity between water and argon takes place, is confirmed. At the same time, there is a region, where the indicated similarity is not observed, and the thermodynamic properties of water demonstrate a peculiar behavior. In particular, an inflection point at a temperature of (91.0 ± 0.2 )C is observed in the temperature dependence of the curve (∂V/∂T)P for water, but not for argon, along the liquid-vapor equilibrium curve. The existence of inflection point in the dependence (∂V/∂T)P for water leads to the presence of negative values of (∂V/∂T)P at temperatures below 3.98C, as well as to the intersection of the temperature dependences of isobars (∂V/∂T)P in water at a temperature of (42 .0 ± 0 .2 )C. On the contrary, the temperature dependences of the curves (∂V/∂T)P for argon along the liquid-vapor equilibrium curve do not have a corresponding inflection point.

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Published

2023-04-20

How to Cite

Bulavin, L., & Rudnikov, Y. (2023). Temperature and Pressure Effect on the Thermodynamics Coefficient (∂V/∂T)p of Water. Ukrainian Journal of Physics, 68(2), 122. https://doi.org/10.15407/ujpe68.2.122

Issue

Section

Physics of liquids and liquid systems, biophysics and medical physics

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