Structure and Electrical Properties of Superionic Ceramics Based on Silver-Enriched (Cu0.25Ag0.75)7SiS5I Solid Solution
DOI:
https://doi.org/10.15407/ujpe66.6.489Keywords:
argyrodite, superionic conductor, ceramic, ionic conductivity, activation energyAbstract
(Cu0.25Ag0.75)7SiS5I-based superionic ceramics were fabricated by using the micro- and nanopowders. The XRD technique and microstructural analysis are applied for the structural studies of powders and ceramic samples. The impedance measurements of ceramic samples are carried out in the frequency range from 10Hz to 2 × 106 Hz and temperature interval from 292 K to 383 K. The contributions of ionic and electronic conductivities into the total electrical conductivity are determined, and their temperature dependences are investigated. The influence of the size effect on ionic and electronic conductivities and their activation energies in (Cu0.25Ag0.75)7SiS5I-based ceramics is studied.
References
M. Bengisu. Applications of ceramic materials. In: Engineering Ceramics. Engineering Materials (Springer, 2001), p. 407-446 [ISBN: 978-3-642-08719-6, 978-3-662-04350-9].
https://doi.org/10.1007/978-3-662-04350-9_6
M. Vallet-Reg'i. Ceramics for medical applications. J. Chem. Soc., Dalton Trans. 2, 97 (2001).
https://doi.org/10.1039/b007852m
Z. Xiao,S. Yu, Y. Li, S. Ruan, L.B. Kong, Q. Huang, Z. Huang, K. Zhou, H. Su, Z. Yao, W. Que, Y. Liu, T. Zhang, J. Wang, P. Liu, D. Shen, M. Allix, J. Zhang, D. Tang. Materials development and potential applications of transparent ceramics: A review. Mater. Sci. Engin.: R: Reports 139, 100518 (2020).
https://doi.org/10.1016/j.mser.2019.100518
R.-Z. Zhang, M.J. Reece. Review of high entropy ceramics: Design, synthesis, structure and properties. J. Mater. Chem. A 7, 22148 (2019).
https://doi.org/10.1039/C9TA05698J
X. Hao. A review on the dielectric materials for high energy-storage application. J. Adv. Dielectr. 3 (1), 1330001 (2013).
https://doi.org/10.1142/S2010135X13300016
V. Fernao Pires, E. Romero-Cadaval, D. Vinnikov, I. Roasto, J.F. Martins. Power converter interfaces for electro-chemical energy storage systems - A review. Energy Conversion and Management 86, 453 (2014).
https://doi.org/10.1016/j.enconman.2014.05.003
Z. Wu, Z. Xie, A. Yoshida, Z. Wang, X. Hao, A. Abudula, G. Guan. Utmost limits of various solid electrolytes in all-
solid-state lithium batteries: A critical review. Renewable and Sustainable Energy Reviews 109, 367 (2019).
https://doi.org/10.1016/j.rser.2019.04.035
J.B. Goodenough, K.-S. Park. The Li-ion rechargeable battery: a perspective. J. Am. Chem. Soc. 135 (4), 1167 (2013).
https://doi.org/10.1021/ja3091438
J. Wen, Y. Yu, C. Chen. A review on lithium-ion batteries safety issues: Existing problems and possible solutions. Mater. Express 2, 197 (2012).
https://doi.org/10.1166/mex.2012.1075
J.W. Fergus. Ceramic and polymeric solid electrolytes for lithium-ion batteries. J. Power Sources 195, 4554 (2010).
https://doi.org/10.1016/j.jpowsour.2010.01.076
Z. Zhang, Q. Zhang, C. Ren, F. Luo, Q. Ma, Y.-S. Hu, Z. Zhou, H. Li, X.H., L. Chen. A ceramic/polymer composite solid electrolyte for sodium batteries. J. Mater. Chem. A 4, 15823 (2016).
https://doi.org/10.1039/C6TA07590H
K.H. Park, D.H. Kim, H. Kwak, S.H. Jung, H.-J. Lee, A. Banerjee, J.H. Lee, Y.S. Jung. Solution-derived glass-ceramic NaI×Na3SbS4 superionic conductors for all-solid-state Na-ion batteries. J. Mater. Chem. A 6, 17192 (2018).
https://doi.org/10.1039/C8TA05537H
M. Tatsumisago, A. Hayashi. Sulfi de glass-ceramic electrolytes for all-solid-state lithium and sodium batteries. Int. J. Appl. Glass Sci. 5, 226 (2014).
https://doi.org/10.1111/ijag.12084
W.F. Kuhs, R. Nitsche, K. Scheunemann. The argyrodites - a new family of the tetrahedrally close-packed structures. Mater. Res. Bull. 14, 241 (1979).
https://doi.org/10.1016/0025-5408(79)90125-9
T. Nilges, A. Pfitzner. A structural diff erentiation of quaternary copper argirodites: Structure- property relations of high temperature ion conductors.Z. Kristallogr. 220, 281 (2005).
https://doi.org/10.1524/zkri.220.2.281.59142
I.P. Studenyak, M. Kranjcec, M.V. Kurik. Urbach rule and disordering processes in Cu6P(S1−xSex)5Br1−yIy superionic conductors.J. Phys. Chem. Solids 67, 807 (2006).
https://doi.org/10.1016/j.jpcs.2005.10.184
H.-J. Deiseroth, S.-T. Kong, H. Eckert, J. Vannahme, C. Reiner, T. Zaib, M. Schlosser. Li6PS5X: A class of crystalline Li-rich solids with an unusually high Li+ mobility. Angew. Chem. Int. Ed. 47, 755 (2008).
https://doi.org/10.1002/anie.200703900
L. Zhou, A. Assoud, Q. Zhang, X. Wu, L.F. Nazar. New family of argyrodite thioantimonate lithium superionic conductors. J. Am. Chem. Soc. 141 (48), 19002 (2019).
https://doi.org/10.1021/jacs.9b08357
H. Wang, C. Yu, S. Ganapathy, E.R.H. van Eck, L. van Eijck, M. Wagemaker. A lithium argyrodite Li6PS5Cl0.5Br0.5 electrolyte with improved bulk and interfacial conductivity. Journal of Power Sources 412, 29 (2019).
https://doi.org/10.1016/j.jpowsour.2018.11.029
Wo Dum Jung, Ji-Su Kim, Sungjun Choi, Seongmin Kim, Minjae Jeon, Hun-Gi Jung, Kyung Yoon Chung, Jong-Ho Lee, Byung-Kook Kim, Jong-Heun Lee, Hyoungchul Kim. Superionic halogen-rich Li-argyrodites using in situ nanocrystal nucleation and rapid crystal growth. Nano Lett. 20 (4), 2303 (2020).
https://doi.org/10.1021/acs.nanolett.9b04597
A.F. Orliukas, E. Kazakevicius, A. Kezionis, T. Salkus, I.P. Studenyak, R.Yu. Buchuk, I.P. Prits, V.V. Panko. Preparation, electric conductivity and dielectrical properties of Cu6PS5I-based superionic composites.Solid State Ionics 180, 183 (2009).
https://doi.org/10.1016/j.ssi.2008.12.005
I.P. Studenyak, V.Yu. Izai, V.I. Studenyak, O.V. Kovalchuk, T.M. Kovalchuk, P. Kop˘cansk'y, M. Timko, N. Tomasovicov'a, V. Zavisova, J. Miskuf, I.V. Oleinikova. Infl uence of Cu 6PS5I superionic nanoparticles on the dielectric properties of 6CB liquid crystal. Liquid Crystals 44, 897 (2017).
https://doi.org/10.1080/02678292.2016.1254288
T. Salkus, E. Kazakevicius, J. Banys, M. Kranjcec, A.A. Chomolyak, Yu.Yu. Neimet, I.P. Studenyak. Influence of grain size effect on electrical properties of Cu 6PS5I superionic ceramics. Solid State Ionics 262, 597 (2014).
https://doi.org/10.1016/j.ssi.2013.10.040
I.P. Studenyak, M.Kranj˘cec, V.Yu. Izai, A.A. Chomolyak, M. Vorohta, V. Matolin, C. Cserhati, S. K¨ok'enyesi. Structural and temperature-related disordering studies of Cu6PS5I amorphous thin fi lms. Thin Solid Films 520, 1729 (2012).
https://doi.org/10.1016/j.tsf.2011.08.043
M.E. Orazem, B. Tribollet. Electrochemical Impedance Spectroscopy. (Wiley, 2008).
https://doi.org/10.1002/9780470381588
I.P. Studenyak, A.I. Pogodin, V.I. Studenyak, V.Yu. Izai, M.J. Filep, O.P. Kokhan, M. Kranjcec, P.K'us. Electrical properties of copper- and silver-containing superionic (Cu1−xAgx)7SiS5I mixed crystals with argyrodite structure. Solid State Ionics 345, 115183 (2020). https://doi.org/10.1016/j.ssi.2019.115183
V.S. Urusov. Theoretical Crystallochemistry (MSU, 1987) (in Russian).
L.B. McCusker, R.B. Von Dreele, D.E. Cox, D. Lou¨er, P. Scardi. Rietveld refi nement guidelines. J. Appl. Crystallogr. 32, 36 (1999). https://doi.org/10.1107/S0021889898009856
A. Altomare, C. Cuocci, C. Giacovazzo, A. Moliterni, R. Rizzi, N. Corriero, A. Falcicchio. EXPO2013: A kit of tools for phasing crystal structures from powder data. J. Appl. Crystallogr. 46, 1231 (2013). https://doi.org/10.1107/S0021889813013113
K. Momma, F. Izumi. VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data. J. Appl. Crystallogr. 44, 1272 (2011). https://doi.org/10.1107/S0021889811038970
A.K. Ivanov-Schitz, I.V. Murin. Solid State Ionics (St.-Petersburg State Univ., 2000) (in Russian).
R.A. Huggins. Simple method to determine electronic and ionic components of the conductivity in mixed conductors: A review. Ionics 8, 300 (2002). https://doi.org/10.1007/BF02376083
Downloads
Published
How to Cite
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.
.png){kind=small}
