Influence of Cation Substitution on Ionic and Electronic Conductivity of (Cu1 – xAgx)7GeS5I Mixed Crystals


  • A.I. Pogodin Uzhhorod National University
  • V.I. Studenyak Uzhhorod National University
  • M.Y. Filep Uzhhorod National University
  • O.P. Kokhan Uzhhorod National University
  • I.P. Studenyak Uzhhorod National University
  • P. Kúš Comenius University



mixed crystals, electrical conductivity, Nyquist plot, activation energy, compositional dependence


Impedance measurements of (Cu1−xAgx)7GeS5I mixed crystals are carried out in the frequency range from 10 Hz to 300 kHz and in the temperature interval 292–383 K. The temperature and frequency dependences of the electrical conductivity for (Cu1−xAgx)7GeS5I mixed crystals are studied. Based on the analysis of Nyquist plots and using the electrode equivalent circuits, the values of ionic and electronic components of the electrical conductivity are determined. The compositional behavior of the ionic and electronic conductivities, as well as the compositional behavior of their activation energies, are discussed. The ratio of ionic and electronic components of the conductivity for (Cu1−xAgx)7GeS5I mixed crystals was analyzed.


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How to Cite

Pogodin, A., Studenyak, V., Filep, M., Kokhan, O., Studenyak, I., & Kúš, P. (2021). Influence of Cation Substitution on Ionic and Electronic Conductivity of (Cu1 – xAgx)7GeS5I Mixed Crystals. Ukrainian Journal of Physics, 66(4), 341.



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