Concerning a Calculation of the Grand Partition Function of a Fluid Model
DOI:
https://doi.org/10.15407/ujpe60.08.0808Keywords:
coexistence curve, collective variables, reference system, simple fluid, equation of stateAbstract
The calculation method of the grand partition function of a simple fluid model in the frame of a generalized lattice model, where each cell may contain a random number of particles, is proposed. As an interaction potential between particles, the Morse potential is chosen. In vcourse of calculations, the summation over the number of particles and the integration over their coordinates are performed. Using the simplest approximation, the equation of state valid in a wide temperature range is obtained. At temperatures lower than the critical one, the presence of horizontal plots on the pressure vs density curve is found.
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Kyiv, Ukraine
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