Electromigration and Diffusion Researches in Scanning Probe Microscopy of Solid Electrolytes

  • A. N. Morozovska Institute of Physics, Nat. Acad. of Sci. of Ukraine
  • V. V. Obukhovskyi Taras Shevchenko National University of Kyiv, Faculty of Radiophysics
  • O. V. Udod I.M. Frantsevych Institute for Problems of Materials Science, Nat. Acad. of Sci. of Ukraine
  • S. V. Kalinin The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory
  • O. Tselev The Center for Nanophase Materials Sciences, Oak Ridge National Laboratory
Keywords: electrochemical strain microscopy, Boltzmann–Planck–Nernst–Einstein approximation, drift-diffusion theory, Vegard’s law

Abstract

The local mechanico-electrochemical response of solid electrolytes has been simulated numerically and analyzed in the Boltzmann–Planck–Nernst–Einstein approximation with regard for the Vegard mechanism. The geometry of the problem is selected to be typical of electrochemical strain microscopy (ESM) experiments. The frequency spectra for various components of the electrolyte surface displacement and the ESM response depth are calculated, as well as the variations of donor concentrations. The corresponding comparative analysis is carried out.

References

S.R. Bishop, K.L. Duncan, and E.D. Wachsman, Electrochim. Acta 54, 1436 (2009).

G.G. Botte, V.R. Subramanian, and R.E. White, Electrochim. Acta 45, 2595 (2000).

N. Balke, S. Jesse, A.N. Morozovska, E. Eliseev, D.W. Chung, Y. Kim, L. Adamczyk, R.E. Garcıa, N. Dudney, and S.V. Kalinin, Nature Nanotechn. 5, 749 (2010).

A. Kumar, F. Ciucci, A.N. Morozovska, S. Kalinin, and S. Jesse, Nature Chem. 3, 707 (2011).

S. Jesse, N. Balke, E. Eliseev, A. Tselev, N.J. Dudney, A.N. Morozovska, and S.V. Kalinin, ACS Nano 5, 9682 (2011).

N. Balke, E.A. Eliseev, S. Jesse, S. Kalnaus, C. Daniel, N.J. Dudney, A.N. Morozovska, and S.V. Kalinin, J. Appl. Phys. 112, 052020 (2012).

A. Kumar, M.T. Arruda, Y. Kim, I.N. Ivanov, S. Jesse, C.W. Bark, N.C. Bristowe, E. Artacho, P.B. Littlewood, C.-B. Eom, and S.V. Kalinin, ACS Nano. 6, 3841 (2012).

N. Balke, S. Jesse, Y. Kim, L. Adamczyk, I.N. Ivanov, N.J. Dudney, and S.V. Kalinin, ACS Nano 4, 7349 (2010).

N. Balke, S. Jesse, Y. Kim, L. Adamczyk, A. Tselev, I.N. Ivanov, N.J. Dudney, and S.V. Kalinin, Nano Lett. 10, 3420 (2010).

A. Gruverman and A. Kholkin, Rep. Prog. Phys. 69, 2443 (2006).

S.V. Kalinin, A.N. Morozovska, L.Q. Chen, and B.J. Rodriguez, Rep. Prog. Phys. 73, 056502 (2010).

A. Kumar, O.S. Ovchinnikov, H. Funakubo, S. Jesse, and S.V. Kalinin, Appl. Phys. Lett. 98, 202903 (2011).

D.B. Strukov, G.S. Snider, D.R. Stewart, and R.S. Williams, Nature 453, 80 (2008).

K. Szot, W. Speier, G. Bihlmayer, and R. Waser, Nat. Mater. 5, 312 (2006).

S. Jesse, H.N. Lee, and S.V. Kalinin, Rev. Sci. Instrum. 77, 073702 (2006).

A.N. Morozovska, E.A. Eliseev, N. Balke, and S.V. Kalinin, J. Appl. Phys. 108, 053712 (2010).

A.N. Morozovska, E.A. Eliseev, A.K. Tagantsev, S.L. Bravina, Long-Qing Chen, and S.V. Kalinin, Phys. Rev. B 83, 195313 (2011).

A.N. Morozovska, E.A. Eliseev, S.V. Kalinin, Appl. Phys. Lett. 96, 222906 (2010).

A.N. Morozovska, E.A. Eliseev, S.L. Bravina, F. Ciucci, G.S. Svechnikov, Long-Qing Chen, and S.V. Kalinin, J. Appl. Phys. 111, 014107 (2012).

N. Balke, S. Jesse, Y. Kim, L. Adamczyk, I.N. Ivanov, N.J. Dudney, and S.V. Kalinin, ACS Nano 4, 7349 (2010).

Y. Gil, O.M. Umurhan, and I. Riess, J. Appl. Phys. 104, 084504 (2008).

M. Molotskii, J. Appl. Phys. 97, 014109 (2005).

B.L. Weeks, M.W. Vaughn, and J.J. DeYoreo, Langmuir 21, 8096 (2005).

J.R. Macdonald, J. Chem. Phys. 58, 4982 (1973).

I. Riess and J. Maier, Phys. Rev. Lett. 100, 205901 (2008).

J. Jamnik and J. Maier, J. Electrochem. Soc. 146, 4183 (1999).

Zhan Chen, J. Electrochem. Soc. 151, A1576 (2004).

http://dx.doi.org/10.1149/1.1789154

H.-Ch. Chang and G. Jaffe, J. Chem. Phys. 20, 1071 (1952).

G. Nanz, in Simulation of Semiconductor Devices and Processes, Vol. 4, edited by W. Fichiner and D. Aemmer (Hartung-Gorre, Zurich, 1991), p. 321.

Y. Gil, O.M. Umurhan, and I. Riess, Solid State Ionics 178, 1 (2007).

A.N. Morozovska, E.A. Eliseev, and S.V. Kalinin, J. Appl. Phys. 111, 014114 (2012).

Published
2019-01-10
How to Cite
Morozovska, A., Obukhovskyi, V., Udod, O., Kalinin, S., & Tselev, O. (2019). Electromigration and Diffusion Researches in Scanning Probe Microscopy of Solid Electrolytes. Ukrainian Journal of Physics, 60(10), 1027. https://doi.org/10.15407/ujpe60.10.1027
Section
Solid matter

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