Nonlinear Diffusion in the Liquid Solution of Diethyl Ether with Chloroform

  • A. M. Kutsyk Taras Shevchenko National University of Kyiv, Faculty of Physics
  • V. V. Obukhovsky Taras Shevchenko National University of Kyiv, Faculty of Physics
Keywords: nonlinear diffusion, mutual diffusion coefficient, complex formation, diethyl ether, chloroform

Abstract

Nonlinear diffusion in the binary liquid solution of diethyl ether with chloroform accompanied by a complex formation reaction has been considered. It is shown that the account for the possibility of the [A1B1] complex formation can explain the nonlinear concentration dependence of the mutual diffusion coefficient. The calculation results are compared with the results of other approaches. A nonlinear modification of Fick’s law was demonstrated to provide the best description of experimental results, i.e. it gives the smallest average relative deviation.

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Published
2019-01-08
How to Cite
Kutsyk, A., & Obukhovsky, V. (2019). Nonlinear Diffusion in the Liquid Solution of Diethyl Ether with Chloroform. Ukrainian Journal of Physics, 61(2), 107. https://doi.org/10.15407/ujpe61.02.0107
Section
Soft matter