Synthesis, Properties, and Application of Graphene-Based Materials Obtained from Carbon Nanotubes and Acetylene Black

  • M. O. Danilov Vernadskyi Institute of General and Inorganic Chemistry, Nat. Acad. of Sci. of Ukraine
  • I. A. Rusetskii Vernadskyi Institute of General and Inorganic Chemistry, Nat. Acad. of Sci. of Ukraine
  • I. A. Slobodyanyuk Vernadskyi Institute of General and Inorganic Chemistry, Nat. Acad. of Sci. of Ukraine
  • G. I. Dovbeshko Institute of Physics, Nat. Acad. of Sci. of Ukraine
  • G. Ya. Kolbasov Vernadskyi Institute of General and Inorganic Chemistry, Nat. Acad. of Sci. of Ukraine
  • Yu. Yu. Stubrov V.E. Lashkaryov Institute of Semiconductor Physics, Nat. Acad. of Sci. of Ukraine
Keywords: graphene oxide, reduced graphene oxide, electrocatalysis, electrode materials for oxygen electrode

Abstract

Graphene oxide and reduced graphene oxide have been chemically synthesized from multiwall carbon nanotubes. Using a proper oxidant, nanotubes can be “unzipped” longitudinally to form graphene oxide nanoribbons. Afterward, reduced graphene oxide can be obtained with the help of a reductant. Standard redox potentials of carbon are used for the selection of an oxidant and a reductant. Various physico-chemical methods are applied to verify the production of graphene-like materials. The synthesized products are used as a material for oxygen electrodes in fuel elements. The electrochemical characteristics of electrodes fabricated from graphene-based materials are found to depend on the redox ability of applied reagents. The obtained materials are shown to be promising catalyst carriers for electrodes in chemical current sources.

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Published
2019-01-04
How to Cite
Danilov, M., Rusetskii, I., Slobodyanyuk, I., Dovbeshko, G., Kolbasov, G., & Stubrov, Y. (2019). Synthesis, Properties, and Application of Graphene-Based Materials Obtained from Carbon Nanotubes and Acetylene Black. Ukrainian Journal of Physics, 61(10), 909. https://doi.org/10.15407/ujpe61.10.0909
Section
Solid matter

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