Peculiarities in the Establishment of Equilibrium State in Diluted Aqueous Solutions of Glycerol

  • L. A. Bulavin Taras Shevchenko National University of Kyiv, Faculty of Physics
  • V. Ya. Gotsulskiy Taras Shevchenko National University of Kyiv, Faculty of Physics
  • V. E. Chechko I.I. Mechnikov National University of Odesa, Scientific and Research Institute of Physics
Keywords: anomalous light scattering, dilute alcohol aqueous solutions, glycerol, thermodynamic equilibrium


The dynamics of the thermodynamic equilibrium establishment in the aqueous solutions of alcohols in a vicinity of specific points is studied on the basis of dilute aqueous solutions of glycerol. At the molar fractions of alcohol x ∼ 0.05, the systems concerned reveal characteristic anomalies testifying to the presence of structural phase transitions. However, the unreliable reproducibility of anomalous light scattering, a phenomenon typical of aqueous alcohol solutions, makes this conclusion debatable. In this work, it was shown that the parameters of aqueous glycerol solutions, which are determined with the help of light scattering phenomenon, become stable only in a certain time interval after the solution preparation. The typical dimensions of optical non-uniformities, the coefficients of scattered light depolarization, and the asymmetry of scattering indicatrix have been found as functions of the time elapsed since the solution preparation.


D.I. Mendeleev, Solutions (Izd. Akad. Nauk SSSR, Moscow, 1956) (in Russian).

V.Y. Gotsulsky, N.P. Malomuzh, and V.E. Chechko, Russ. J. Phys. Chem. A 87, 1638 (2013).

V.E. Chechko, V.Ya. Gotsulsky, and M.P. Malomuzh, Cond. Matter Phys. 16, 23006 (2013).

M.A. Anisimov, Critical Phenomena in Liquids and Liquid Crystals (Gordon and Breach, Philadelphia, 1991).

M.F. Vuks, Mol. Fiz. Biofiz. Vodn. Syst. 7, 172 (1989).

V.A. Durov and I.Yu. Shipov, Zh. Fiz. Khim. 72, 1245 (1989).

M.F. Vuks, Mol. Fiz. Biofiz. Vodn. Syst. 6, 3 (1986).

M.I. Shakhparonov and M.V. Chekalin, Zh. Strukt. Khim. 11, 599 (1970).

T. Ramanjappa amd E. Rajagopiab, Bull. Chem. Soc. Jpn. 61, 2171 (1988).

M.B. Vinnichenko and M.F. Vuks., Fiz. Zhidk. Sost.14, 63 (1986).

K. Nakanishi, Bull. Chem. Soc. Jpn. 33, 793 (1960).

C. Visser, G. Perron, and J. E. Desnovers, Can. J. Chem. 55, 856 (1977).

C.J. Burton, J. Acoust. Soc. Am. 20, 186 (1948).

G.A. Krestov, B.E. Nedelka, and V.P. Slyusar, Izv. Vyssh. Ucheb. Zaved. Khim. Tekhnol. 19, 1629 (1976).

V.A. Mikhailov and E.F. Grigorieva, Zh. Strukt. Khim. 9, 788 (1968).

M.A. Anisimov et al., Zh. Strukt. Khim. 18, 835 (1977).

Physical Acoustics. Principles and Methods, Vol. 2A: Properties of Gases, Liquids, and Solutions, edited by W.P. Mason (Academic Press, New York, 1965).

L.V. Lanshina and G.M. Dakar, Zh. Fiz. Khim. 70, 411 (1996).

H. Endo, Bull. Chem. Soc. Jpn. 46, 1106 (1973).

L.V. Lanshina and A.L. Sobirov, Vestn. Mosk. Gos. Univ. 30, 210 (1989).

L.V. Lanshina and A.I. Abramovich, Zh. Fiz. Khim. 79, 711 (2005).

V.M. Belyakova, M.F. Vuks, and V.L. Rapoport, Zh. Strukt. Khim. 18, 297 (1977).

I.Ya. Kochnev and A.I. Khaloimov, Zh. Strukt. Khim. 14, 791 (1973).

M.F. Vuks, Light Scattering in Gases, Liquids, and Solutions (Leningrad Univ., Leningrad, 1977) (in Russian).

M.F. Vuks and L.V. Shurupova, Opt. Spektrosk. 40, 154 (1976).

V.E. Eskin and A.E. Nesterov, Ukr. Fiz. Zh. 9, 540 (1964).

L.M. Sabirov, D.I. Semenov, and Kh.S. Khaydarov, Opt. Spectrosc. 105, 369 (2008).

C.W. Beer and D.J. Jolly, Opt. Commun. 11, 150 (1974).

G.P. Roshchina and A.S. Kaurova, Ukr. Fiz. Zh. 9, 512 (1964).

D. Subramanian and M.A. Anisimov, J. Phys. Chem. B 115, 9179 (2011).

V.E. Chechko, V.Ya. Gotsulskiy, and V.G. Zaremba, J. Mol. Liq. 105, 211 (2003).

V.E. Chechko, Ukr. Fiz. Zh. 46, 920 (2001).

V.E. Chechko and V.G. Zaremba, Khim. Fiz. 12, 1036 (1993).

M. Volmer, Kinetik der Phasenbildung (Steinkopf, Dresden, 1939).

V.E. Chechko, V.G. Zaremba, and V.Ya. Gotsul'sky, J. Mol. Liq. 93, 35 (2001).

Photo Correlation and Light Beating Spectroscopy, edited by H.Z. Cummins and E.R. Pike (Plenum Press, New York, 1974).

V.Ya. Gotsul'skii, V.E. Chechko, and V.G. Zaremba, Prib. Tekhn. Eksp. 2, 161 (1997).

P. Debye, J. Chem. Phys. 31, 680 (1959).

N.Yu. Golubovskii and G.P. Roshchina, Ukr. Fiz. Zh. 9, 531 (1964).

How to Cite
Bulavin, L., Gotsulskiy, V., & Chechko, V. (2018). Peculiarities in the Establishment of Equilibrium State in Diluted Aqueous Solutions of Glycerol. Ukrainian Journal of Physics, 59(7), 689.
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