Peculiarities of Electronic Processes in High-Fluorescence Boron-Containing Composite Films

  • V. M. Yashchuk Faculty of Physics, Taras Shevchenko National University of Kyiv
  • O. M. Navozenko Faculty of Physics, Taras Shevchenko National University of Kyiv
  • Yu. L. Slominskii Institute of Organic Chemistry, Nat. Acad. of Sci. of Ukraine
  • J. V. Grazulevicius Department of Organic Technology, Kaunas University of Technology
  • O. D. Kachkovsky Institute of Organic Chemistry, Nat. Acad. of Sci. of Ukraine
  • A. P. Naumenko Faculty of Physics, Taras Shevchenko National University of Kyiv
Keywords: cyanine dyes, vacuum deposition, thin films, OLED, boron-containing complexes

Abstract

The absorption and fluorescence spectra of new boron-containing dyes in pure thin films of these dyes, as well as in double-components films of the “matrix–dye (impurity)” type, are studied. As matrix materials, tris(8-hydroxyquinolinato)aluminum (Alq3) and 3,6-di(9-carbazolyl)-9-(2-ethylhexyl) carbazole (Tcz1) are used. The thin films were obtained by the method of vacuum deposition. The comparison of the absorption spectra of the dyes in solutions and films shows that the destruction of dye molecules is not observed in the process of vacuum deposition. For double-component films, the electronic excitation energy transfer from matrix molecules to dye molecules is established. The optimum concentration of dyes for the light-emitting layers of organic light-emitting diodes (OLEDs) based on these compounds is determined.

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Published
2018-10-19
How to Cite
Yashchuk, V., Navozenko, O., Slominskii, Y., Grazulevicius, J., Kachkovsky, O., & Naumenko, A. (2018). Peculiarities of Electronic Processes in High-Fluorescence Boron-Containing Composite Films. Ukrainian Journal of Physics, 59(3), 238. https://doi.org/10.15407/ujpe59.03.0238
Section
Optics, lasers, and quantum electronics

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