Fullerene Clustering in C70/N-Methyl-2-Pyrrolidone/Toluene Liquid System

Authors

  • L. A. Bulavin Taras Shevchenko National University of Kyiv, Institute for Safety Problems of Nuclear Power Plants, Nat. Acad. of Sci. of Ukraine
  • T. V. Nagorna Taras Shevchenko National University of Kyiv, Joint Institute for Nuclear Research
  • O. A. Kyzyma Taras Shevchenko National University of Kyiv, Joint Institute for Nuclear Research
  • D. Chudoba Joint Institute for Nuclear Research, Uniwersytet im. Adama Mickiewicza w Poznaniu
  • O. I. Ivankov Institute for Safety Problems of Nuclear Power Plants, Nat. Acad. of Sci. of Ukraine
  • A. V. Nagornyi Taras Shevchenko National University of Kyiv, Joint Institute for Nuclear Research
  • M. V. Avdeev Joint Institute for Nuclear Research

DOI:

https://doi.org/10.15407/ujpe63.2.116

Keywords:

C70 fullerene clustering, small-angle neutron scattering

Abstract

The structural behavior of the liquid system based on a C70 in an N-methyl-2-pyrrolidone–toluene mixture has been analyzed, by using the small-angle neutron scattering method. The experimental results testify to the selective solvation in the system. The corresponding mechanisms have been discussed.

References

<ol><li>L. Wang. Solvated fullerenes, a new class of carbon materials suitable for high-pressure studies: A review. J. Phys. Chem. Solids 84, 85 (2015).
<a href="https://doi.org/10.1016/j.jpcs.2014.06.007">https://doi.org/10.1016/j.jpcs.2014.06.007</a>
</li>
<li>M. Xing, R. Wang, J. Yu. Application of fullerene C60 nano-oil for performance enhancement of domestic refrigerator compressors. Int. J. Refrig. 40, 398 (2014).
<a href="https://doi.org/10.1016/j.ijrefrig.2013.12.004">https://doi.org/10.1016/j.ijrefrig.2013.12.004</a>
</li>
<li>S. Afreen, K. Muthoosamy, S. Manickam et al. Functionalized fullerene (C60) as a potential nanomediator in the fabrication of highly sensitive biosensors. Biosens. Bioelectr. 63, 354 (2015).
<a href="https://doi.org/10.1016/j.bios.2014.07.044">https://doi.org/10.1016/j.bios.2014.07.044</a>
</li>
<li>A.V. Eletskii, B.M. Smirnov. Fullerenes and carbon structure. Usp. Fiz. Nauk 165, 977 (1995) (in Russian).
<a href="https://doi.org/10.3367/UFNr.0165.199509a.0977">https://doi.org/10.3367/UFNr.0165.199509a.0977</a>
</li>
<li>Y. Marcus. Solubilities of buckminsterfullerene and sulfur hexafluoride in various solvents. J. Phys. Chem. 101, 942 (1997).
<a href="https://doi.org/10.1021/jp970671s">https://doi.org/10.1021/jp970671s</a>
</li>
<li>Y. Marcus, A.L. Smith, M.V. Korobov et al. Solubility of C60 fullerene. J. Phys. Chem. B 105, 13 (2001).
<a href="https://doi.org/10.1021/jp0023720">https://doi.org/10.1021/jp0023720</a>
</li>
<li>A.N. Kinchin, A.M. Kolker, N.I Islamova. Correlation between the thermodynamic parameters of fullerene C60 solution and the properties of non-aqueous solvents. Zh. Fiz. Khim. 76, 1772 (2002) (in Russian).
</li>
<li>J. Labille, J. Brant, F. Villieras et al. Affinity of C60 fullerenes with water. Fulleren. Nanotub. Carbon Nanostruct. 14, 307 (2006).
<a href="https://doi.org/10.1080/15363830600665250">https://doi.org/10.1080/15363830600665250</a>
</li>
<li>I.E. Serdyuk, I.V. Belochkina, A.P. Kryshtal, A.D. Roshal, I.M. Neklyudov, B.V. Borshch, V.N. Voevodin, V.I. Tkachenko, B.P. Sandomirskii. Production and biological activity of aqueous colloidal solutions of C60 and C70 fullerene mixtures. Biotekhnologiya 4, 64 (2011) (in Russian).
</li>
<li> S. Yang, X. Mulet, T. Gengenbach et al. Limitations with solvent exchange methods for synthesis of colloidal fullerenes. Colloid. Surface. A 514, 21 (2017).
<a href="https://doi.org/10.1016/j.colsurfa.2016.11.021">https://doi.org/10.1016/j.colsurfa.2016.11.021</a>
</li>
<li> R.-H. Guo, C.-C. Hua, P.-C. Lin, T.-Y. Wang, S.-A. Chen. Mesoscale aggregation properties of C60 in toluene and chlorobenzene, Soft Matter 12, 6300 (2016).
<a href="https://doi.org/10.1039/C6SM00602G">https://doi.org/10.1039/C6SM00602G</a>
</li>
<li> U. Makhmanov, O. Ismailova, A. Kokhkharov et al. Features of self-aggregation of C60 molecules in toluene prepared by different methods. Phys. Lett. A 380, 2081 (2016).
<a href="https://doi.org/10.1016/j.physleta.2016.04.030">https://doi.org/10.1016/j.physleta.2016.04.030</a>
</li>
<li> A.V. Eletskii, B.M. Smirnov. Fullerenes in solutions, Usp. Fiz. Nauk 168, 1195 (1995).
</li>
<li> S. Nath, H. Pal, A. Sapre. Effect of solvent polarity on the aggregation of C60. Chem. Phys. Lett. 327, 143 (2000).
<a href="https://doi.org/10.1016/S0009-2614(00)00863-0">https://doi.org/10.1016/S0009-2614(00)00863-0</a>
</li>
<li> S. Nath, H. Pal, A. Sapre. Effect of solvent polarity on the aggregation of fullerenes: a comparison between C60 and C70. Chem. Phys. Lett. 360, 422 (2002).
<a href="https://doi.org/10.1016/S0009-2614(02)00780-7">https://doi.org/10.1016/S0009-2614(02)00780-7</a>
</li>
<li> N.O. Mchedlov-Petrossyan, N.N. Kamneva, Y.T.M. Al-Shuuchi, A.I. Marynin, S.V. Shekhovtsov. The peculiar behavior of fullerene C60 in mixtures of 'good' and polar solvents: Colloidal particles in the toluene–methanol mixtures and some other systems. Colloid. Surface. A 509 631 (2016).
<a href="https://doi.org/10.1016/j.colsurfa.2016.09.045">https://doi.org/10.1016/j.colsurfa.2016.09.045</a>
</li>
<li> M. Alf’e, B. Apicella, R. Barbella, A. Bruno, A. Ciajolo. Aggregation and interactions of C60 and C70 fullerenes in neat N-methylpyrrolidinone and in N-methylpyrrolidinone/toluene mixtures. Chem. Phys. Lett. 405, 193 (2005).
<a href="https://doi.org/10.1016/j.cplett.2005.02.030">https://doi.org/10.1016/j.cplett.2005.02.030</a>
</li>
<li> M. Alf’e, R. Barbella, A. Bruno, P. Minutolo, A. Ciajolo. Solution behaviour of C60 fullerene in N-methylpyrrolidinone/toluene mixtures. Carbon 43, 665 (2005).
<a href="https://doi.org/10.1016/j.carbon.2004.10.017">https://doi.org/10.1016/j.carbon.2004.10.017</a>
</li>
<li> V.L. Aksenov, T.V. Tropin, O.A. Kyzyma, M.V. Avdeev, M.V. Korobov, L. Roshta. To fullerene C60 clustering in nitrogen-containing solvents. Fiz. Tverd. Tela 52, 992 (2010) (in Russian).
</li>
<li> O.A. Kyzyma, M.V. Korobov, M.V. Avdeev, V.M. Garamus, V.I. Petrenko, V.L. Aksenov, L.A. Bulavin. Solvatochromism and fullerene cluster formation in C60/N-methyl-2-pyrrolidone. Fulleren. Nanotub. Carbon Nanostruct.18, 458 (2010).
<a href="https://doi.org/10.1080/1536383X.2010.487778">https://doi.org/10.1080/1536383X.2010.487778</a>
</li>
<li> T.V. Nagorna, O.A. Kyzyma, D.Chudoba, A.V. Nagornyi. Temporal solvatochromic effect in ternary C70/toluene/N-methyl-pyrrolidine-2-one solution. J. Mol. Liq. 235, 111 (2017).
<a href="https://doi.org/10.1016/j.molliq.2016.12.017">https://doi.org/10.1016/j.molliq.2016.12.017</a>
</li>
<li> M.V. Avdeev, V.L. Aksenov, T.V. Tropin. Models of fullerene clustering in solutions. Zh. Fiz. Khim. 84, 1405 (2010) (in Russian).
</li>
<li> N.O. Mchedlov-Petrossyan. Fullerenes in molecular liquids. Solutions in "good" solvents: Another view. J. Mol. Liq. 161, 1 (2011).
<a href="https://doi.org/10.1016/j.molliq.2011.04.001">https://doi.org/10.1016/j.molliq.2011.04.001</a>
</li>
<li> C.M. Sayes, J.D. Fortner, W. Guo, D. Lyon, A.M. Boyd, K.D. Ausman, Y.J. Tao, B. Sitharaman, L.J. Wilson, J.B. Hughes, J.L. West, V.L. Colvin. The differential cytotoxicity of water-soluble fullerenes. Nano Lett. 4, 1881 (2004).
<a href="https://doi.org/10.1021/nl0489586">https://doi.org/10.1021/nl0489586</a>
</li>
<li> O.A. Kyzyma, A.V. Tomchuk, M.V. Avdeev, T.V. Tropin, V.L. Aksenov, M.V. Korobov. Structural researches of carbonic fluid nanosystems. Ukr. J. Phys. 60, 835 (2015).
<a href="https://doi.org/10.15407/ujpe60.09.0835">https://doi.org/10.15407/ujpe60.09.0835</a>
</li>
<li> T.V. Tropin, M.V. Avdeev, O.A. Kyzyma, V.L. Aksenov. Nucleation theory models for describing kinetics of cluster growth in C60/NMP solutions. Phys. Status Solidi B 247, 3022 (2010).
<a href="https://doi.org/10.1002/pssb.201000119">https://doi.org/10.1002/pssb.201000119</a>
</li>
<li> T.V. Tropin, N. Jargalan, M.V. Avdeev, O.A. Kyzyma, R.A. Eremin, D. Sangaa, V.L. Aksenov. Kinetics of cluster growth in polar solutions of fullerene: Experimental and theoretical study of C60/NMP solution. J. Mol. Liq. 175, 4 (2012).
<a href="https://doi.org/10.1016/j.molliq.2012.08.003">https://doi.org/10.1016/j.molliq.2012.08.003</a>
</li>
<li> S. Andreev, D. Purgina, E. Bashkatova et al. Study of fullerene aqueous dispersion prepared by novel dialysis method: simple way to fullerene aqueous solution. Fulleren. Nanotub. Carbon Nanostruct. 23, 7 (2015).
<a href="https://doi.org/10.1080/1536383X.2014.998758">https://doi.org/10.1080/1536383X.2014.998758</a>
</li>
<li> N.P. Yevlampieva, Yu.F. Biryulin, E.Yu. Melenevskaja, V.N. Zgonnik, E.I. Rjumtsev. Aggregation of fullerene C60 in N-methylpyrrolidone. Colloid. Surface. A 209, 167 (2002).
<a href="https://doi.org/10.1016/S0927-7757(02)00177-2">https://doi.org/10.1016/S0927-7757(02)00177-2</a>
</li>
<li> A.I. Kuklin, D.V. Soloviov, A.V. Rogachev et al. New opportunities provided by modernized small-angle neutron scattering two-detector system instrument (YuMO). J. Phys. Conf. Ser. 291, 1 (2011).
<a href="https://doi.org/10.1088/1742-6596/291/1/012013">https://doi.org/10.1088/1742-6596/291/1/012013</a>
</li>
<li> Yu.I. Prylutskyy, V.I. Petrenko, O.I. Ivankov, O.A. Kyzyma, L.A. Bulavin, O.O. Litsis, M.P. Evstigneev, V.V. Cherepanov, A.G. Naumovets, U. Ritter. On the origin of C60 fullerene solubility in aqueous solution. Langmuir 30, 3967 (2014).
<a href="https://doi.org/10.1021/la404976k">https://doi.org/10.1021/la404976k</a>
</li>
<li> A.G. Soloviev, T.M. Solovieva, A.V. Stadnik et al. The upgrade of package for preliminary treatment of small-angle scattering spectra. JINR Commun. 10, 2003 (2003).
</li>
<li> A.A. Kaznacheevskaya, O.A. Kizima, L.A. Bulavin, A.V. Tomchuk,V.M. Garamus, M.V. Avdeev. Reorganization of the cluster state in a C60/N-methylpyrrolidone/water solution: Comparative characteristics of dynamic light scattering and small-angle neutron scattering data. J. Surf. Invest. X-ray Synchr. Neutr. Techn. 7, 1133 (2013).
</li>
<li> . Sivaraman, R. Dhamodaran, I. Kaliappan et al. Solubility of C70 in organic solvents. Fullerene Sci. Technol. 2 (3), 233 (1994).
<a href="https://doi.org/10.1080/15363839408009549">https://doi.org/10.1080/15363839408009549</a>
</li>
<li> T.V. Tropin, T.O. Kyrey, O.A. Kyzyma, A.V. Feoktistov, M.V. Avdeev, L.A. Bulavin, L. Rosta, V.L. Aksenov. Experimental investigation of C60/NMP/toluene solutions by UV-Vis spectroscopy and small-angle neutron scattering, J. Surf. Invest. X-ray, Synchrotron Neutron Techn. 7, 1 (2013).
<a href="https://doi.org/10.1134/S1027451013010199">https://doi.org/10.1134/S1027451013010199</a>
</li>
<li> O.A. Kyzyma, M.V. Korobov, M.V. Avdeev, V.M. Garamus, S.V. Snegir, V.I. Petrenko, V.L. Aksenov, L.A. Bulavin. Aggregate development in C60/N-metyl-2-pyrrolidone solution and its mixture with water as revealed by extraction and mass spectroscopy. Chem. Phys. Lett. 493, 103 (2010).
<a href="https://doi.org/10.1016/j.cplett.2010.04.076">https://doi.org/10.1016/j.cplett.2010.04.076</a>
</li>
<li> O.A. Kyzyma, L.A. Bulavin, V.L. Aksenov, M.V. Avdeev, T.V. Tropin, M.V. Korobov, S.V. Snegir, L. Rosta. Aggregation in C60/NMP, C60/NMP/water and C60/NMP/toluene mixtures. Fulleren. Nanotub. Carbon Nanostruct. 16, 610 (2008).
<a href="https://doi.org/10.1080/15363830802312982">https://doi.org/10.1080/15363830802312982</a>
</li>
<li> T.O. Kyrey, O.A. Kyzyma, M.V. Avdeev, T.V. Tropin, M.V. Korobov, V.L. Aksenov, L.A. Bulavin. Absorption characteristics of fullerene C60 in N-methyl-2-pirrolidone/toluene mixture. Fulleren. Nanotub. Carbon Nanostruct. 20, 341 (2012).
<a href="https://doi.org/10.1080/1536383X.2012.655173">https://doi.org/10.1080/1536383X.2012.655173</a>
</li>
<li> O.A. Kyzyma, T.O. Kyrey, M.V. Avdeev, M.V. Korobov, L.A. Bulavin, V.L. Aksenov. Non-reversible solvatochromism in N-methyl-2-pyrrolidone/toluene mixed solutions of fullerene C60. Chem. Phys. Lett. 556, 178 (2013).
<a href="https://doi.org/10.1016/j.cplett.2012.11.040">https://doi.org/10.1016/j.cplett.2012.11.040</a></li></ol>

Published

2018-03-10

How to Cite

Bulavin, L. A., Nagorna, T. V., Kyzyma, O. A., Chudoba, D., Ivankov, O. I., Nagornyi, A. V., & Avdeev, M. V. (2018). Fullerene Clustering in C70/N-Methyl-2-Pyrrolidone/Toluene Liquid System. Ukrainian Journal of Physics, 63(2), 116. https://doi.org/10.15407/ujpe63.2.116

Issue

Section

Physics of liquids and liquid systems, biophysics and medical physics

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