Fluorescence Intensity Response of Fumed Silica Films with Immobilized 7-hydroxy-4-methylcoumarin to Acetone Microconcentrations in Air

Authors

  • Ya.P. Lazorenko V.G. Baryakhtar Institute of Magnetism of the Nat. Acad. of Sci. of Ukraine
  • V.O. Sokolov V.G. Baryakhtar Institute of Magnetism of the Nat. Acad. of Sci. of Ukraine
  • S.V. Kryvets V.G. Baryakhtar Institute of Magnetism of the Nat. Acad. of Sci. of Ukraine
  • S.O. Mamilov V.G. Baryakhtar Institute of Magnetism of the Nat. Acad. of Sci. of Ukraine

DOI:

https://doi.org/10.15407/ujpe70.4.237

Keywords:

acetone, adsorption, coumarin dyes, fluorescence, fumed silica, optical chemical sensor

Abstract

The spectral-fluorescence properties of the 7-hydroxy-4-methylcoumarin (Cou4) dye dissolved in ethanol and immobilized in the fumed silica (A-380 aerosil) sorbent in the form of films and their changes upon interaction with acetone molecules have been investigated. The dependence of the change in fluorescence intensity of such film samples on the concentrations of acetone and ethanol in the air in the 3–15 ppm range has been determined. The obtained results indicate the possibility of using the films for the sensory determination of acetone in the air selectively to simple alcohols (ethanol), particularly, for non-invasive diagnosis of diabetes by analyzing the exhaled human air.

References

1. Chunyan Li, Pil Gyu Choi, Kyusung Kim, Yoshitake Masuda. High performance acetone ga sensor based on ultrathin porous NiO nanosheet. Sensor. Actuat. B-Chem. 367, 132143 (2022).

https://doi.org/10.1016/j.snb.2022.132143

2. V. Saasa, Th. Malwela, M. Beukes, M. Mokgotho, ChaunPu Liu, B. Mwakikunga. Sensing technologies for detection of acetone in human breath for diabetes diagnosis and monitoring. Diagnostics 8, 12 (2018).

https://doi.org/10.3390/diagnostics8010012

3. A.M. Poff, J.M. Rho, D.P. D'Agostino. Ketone administration for seizure disorders: History and rationale for ketone esters and metabolic alternatives. Front. Neurosci.-Switz. 13, 1041 (2019).

https://doi.org/10.3389/fnins.2019.01041

4. A. Prabhakar, A. Quach, Di Wang, Haojiong Zhang, M. Terrera, D. Jackemeyer, Xiaojun Xian, F. Tsow, Nongjian Tao, E.S. Forzani. Breath acetone as biomarker for lipid oxidation and early ketone detection. Glob. J. Obes. Diabetes Metab. Syndr. 1, 12 (2014).

https://doi.org/10.17352/2455-8583.000003

5. B.A. Mamyrin. Time-of-flight mass spectrometry (concepts, achievements, and prospects). Int. J. Mass Spectrom. 206, 251 (2001).

https://doi.org/10.1016/S1387-3806(00)00392-4

6. Guangjie Song, Di Jiang, Jianchang Wu, Xiangzhong Sun, Mengyu Deng, Lei Wang, Changxiang Hao, Jiayan Shi, Hongtian Liu, Yanqing Tian, Meiwan Chen. An ultrasensitive fluorescent breath ammonia sensor for noninvasive diagnosis of chronic kidney disease and helicobacter pylori infection. Chem. Eng. J. 440, 135979 (2022).

https://doi.org/10.1016/j.cej.2022.135979

7. R. Selvaraj, N.J. Vasa, S.M.Sh. Nagendra, B. Mizaikoff. Advances in mid-infrared spectroscopy-based sensing techniques for exhaled breath diagnostics. Molecules 25, 2227 (2020).

https://doi.org/10.3390/molecules25092227

8. M. Alshareef, R.M. Snari, O. Alaysuy, A.M. Aldawsari, H.M. Abumelha, H. Katouah, N.M. El-Metwaly. Optical detection of acetone using "turn-off" fluorescent rice straw based cellulose carbon dots imprinted onto paper dipstick for diabetes monitoring. ACS Omega 7, 16766 (2022).

https://doi.org/10.1021/acsomega.2c01492

9. Yanyu Qi, Wenjun Xu, Nannan Ding, Xingmao Chang, Congdi Shang, Haonan Peng, Taihong Liu, Yu Fang. A film-based fluorescent device for vapor phase detection of acetone and related peroxide explosives. Mater. Chem. Front. 3, 1218 (2019).

https://doi.org/10.1039/C9QM00095J

10. Zheng Qiuying, Guo Wu, Lin Xue, Li Ming. Silica aerogel loaded with novel fluorescent probe applied for formaldehyde detection. New Chemical Materials 49, 222 (2021).

11. C.M.R. Almeida, J. Pina, J.M.C.S. Magalhaes, M.F. Barroso, L. Duraes. One-pot synthesis of lanthanide-doped silica film as a ratiometric fluorescent probe for selective amine vapours detection. Opt. Mater.: X 145, 114396 (2023).

https://doi.org/10.1016/j.optmat.2023.114396

12. R. Mesin, Cheng-Shane Chu, Zong-Liang Tseng. Ratiometric optical oxygen sensor based on perovskite quantum dots and Rh110 embedded in an ethyl cellulose matrix. Opt. Mater. Express 13, 945 (2023).

https://doi.org/10.1364/OME.487332

13. A. Revilla-Cuesta, I. Abajo-Cuadrado, M. Medrano, M.M. Salgado, M. Avella, M.T. Rodriguez, J. Garcia-Calvo, T. Torroba. Silica nanoparticle/fluorescent dye assembly capable of ultrasensitively detecting airborne triacetone triperoxide: Proof-of-concept detection of improvised explosive devices in the workroom. ACS Appl. Mater. Inter. 15, 32024 (2023).

https://doi.org/10.1021/acsami.3c05931

14. D. Khan, Shaily. Coumarin-based fluorescent sensors. Appl. Organomet. Chem. 37, e7138 (2023).

https://doi.org/10.1002/aoc.7138

15. B.D. Wagner. The use of coumarins as environmentallysensitive fluorescent probes of heterogeneous inclusion systems. Molecules 14, 210 (2009).

https://doi.org/10.3390/molecules14010210

16. E.R. Ale, A. Olives, L. Martin, M. Martin, B. del Castillo, A. Agnese, M. Ortega, S. Nunez-Montoya, J.L. Cabrera. Estudio del efecto solvatocromico en derivados fenolicos naturals. Ars Pharm. 43, 57 (2002).

17. V.K. Sharma, D. Mohan, P.D. Sahare. Fluorescence quenching of 3-methyl 7-hydroxyl coumarin in presence of acetone. Spectrochim. Acta A 66, 111 (2007).

https://doi.org/10.1016/j.saa.2006.02.032

18. N. Cabaleiro, I. de la Calle, C. Bendicho, I. Lavilla. Coumarins as turn on/off fluorescent probes for detection of residual acetone in cosmetics following headspace singledrop microextraction. Talanta 129, 113 (2014).

https://doi.org/10.1016/j.talanta.2014.05.033

19. V.P. Mitsai, Ya.P. Lazorenko, A.G. Misyura, S.O. Mamilov. Gas-sensing fluorescent nanostructured composites with coumarin dyes and CdTe semiconductor nanoparticles for non-invasive medical diagnostics. Nanosist. Nanomater. Nanotehnol. 19, 941 (2021).

https://doi.org/10.15407/nnn.19.04.941

20. M. Gerboles, E. Diaz, A. Noriega-Guerra. Uncertainty calculation and implementation of the static volumetric method for the preparation of NO and SO2 standard gas mixtures. Accredit. Qual. Assur. 3, 69 (1998).

https://doi.org/10.1007/s007690050188

21. D.E. Schlamadinger, D.I. Kats, J.E. Kim. Quenching of tryptophan fluorescence in unfolded cytochrome c: A biophysics experiment for physical chemistry students. J. Chem. Educ. 87, 961 (2010).

https://doi.org/10.1021/ed900029c

22. L.K. Fraiji, D.M. Hayes, T.C. Werner. Static and dynamic fluorescence quenching experiments for the physical chemistry laboratory. J. Chem. Educ. 69, 424 (1992).

https://doi.org/10.1021/ed069p424

23. F. Babick, S. Gropp, U. Katzel, M. Vorbau. Dynamic light scattering of dispersed fumed silica aggregates. Powder Technol. 217, 39 (2012).

https://doi.org/10.1016/j.powtec.2011.10.064

Published

2025-04-25

Issue

Section

Optics, atoms and molecules

How to Cite

Fluorescence Intensity Response of Fumed Silica Films with Immobilized 7-hydroxy-4-methylcoumarin to Acetone Microconcentrations in Air. (2025). Ukrainian Journal of Physics, 70(4), 237. https://doi.org/10.15407/ujpe70.4.237