Lamellar Gels: Structural Peculiarities

Authors

  • Yu.F. Zabashta Taras Shevchenko National University of Kyiv, Faculty of Physics
  • V.I. Kovalchuk Taras Shevchenko National University of Kyiv, Faculty of Physics
  • L.A. Bulavin Taras Shevchenko National University of Kyiv, Faculty of Physics

DOI:

https://doi.org/10.15407/ujpe70.7.470

Keywords:

lamellar gel, hydroxypropylcellulose, light scattering

Abstract

The possibility of the existence of lamellar gels has been formulated using the topological approach. The structural peculiarity of the gels of this type consists in that their framework is formed by lamellae. A model of an ideal lamellar gel has been proposed, and its structural parameters have been calculated. The type of defects that can emerge in a real lamellar gel has been determined. A formula has been derived that describes water transport through the surface of lamellar hydrogels. The possibility of the existence of lamellar gels has been confirmed experimentally via light scattering in the aqueous solution of hydroxypropyl cellulose.

References

1. P.-G. Gennes. Scaling Concepts in Polymer Physics (Cornell University Press, 1979).

2. E. Cal'o, V.V. Khutoryanskiy. Biomedical applications of hydrogels: A review of patents and commercial products. Eur. Polym. J. 65, 252 (2014).

https://doi.org/10.1016/j.eurpolymj.2014.11.024

3. R. Barbucci. Hydrogels: Biological Properties and Applications (Springer-Verlag, 2009).

https://doi.org/10.1007/978-88-470-1104-5

4. S. Rimmer. Biomedical Hydrogels: Biochemistry, Manufacture and Medical Applications (Woodhead Publ., 2016).

5. N.A. Peppas. Hydrogels in Medicine and Pharmacy: Properties and Applications (Routledge Revivals) (CRC Press Inc., 2019).

https://doi.org/10.1201/9780429285097

6. M. Karg, A. Pich, T. Hellweg, T. Hoare, L.A. Lyon, J.J. Crassous, D. Suzuki, R.A. Gumerov, S. Schneider, I.I. Potemkin, W. Richtering. Nanogels and microgels: from model colloids to applications, recent developments, and future trends. Langmuir 35, 6231 (2019).

https://doi.org/10.1021/acs.langmuir.8b04304

7. T. Okano. Biorelated Polymers and Gels: Controlled Release and Applications in Biomedical Engineering (Polymers, Interfaces and Biomaterials) (Academic Press, 1998).

8. K. Kamide. Cellulose and Cellulose Derivatives: Molecular Characterization and its Applications (Elsevier Science, 2005).

9. S.M.F. Kabir, P.P. Sikdar, B. Haque, M.A.R. Bhuiyan, A. Ali, M.N. Islam. Cellulose-based hydrogel materials: chemistry, properties and their prospective applications. Prog. Biomater. 7, 153 (2018).

https://doi.org/10.1007/s40204-018-0095-0

10. A.R. Khokhlov, A.Yu. Grosberg, V.S. Pande. Statistical Physics of Macromolecules (American Institute of Physics, 1994).

11. K. Kuratowski. Introduction to Set Theory and Topology (Pergamon Press, 1972).

https://doi.org/10.1016/B978-0-08-016160-0.50014-2

12. J.M. Ziman. Models of Disorder: The Theoretical Physics of Homogeneously Disordered Systems (Cambridge University Press, 1979).

13. J.M. Ziman. Principles of the Theory of Solids (Manohar Publishers and Distributors, 2013).

14. L.A. Bulavin, O.Yu. Aktan, Y.F. Zabashta. Vacancies in oligomer crystals. Polym. Sci. Ser. A 51, 1023 (2009).

https://doi.org/10.1134/S0965545X09090090

15. V.I. Kovalchuk, O.M. Alekseev, M.M. Lazarenko. Turbidimetric monitoring of phase separation in aqueous solutions of thermoresponsive polymers. J. Nano-Electron. Phys. 14, 01004 (2022).

https://doi.org/10.21272/jnep.14(1).01004

16. B. Wunderlich. Macromolecular Physics (Academic Press, 2013).

17. Yu.F. Zabashta, V.I. Kovalchuk, O.S. Svechnikova, L.A. Bulavin. Determination of the surface tension coefficient of polymer gel. Ukr. J. Phys. 67, 365 (2022).

https://doi.org/10.15407/ujpe67.5.365

18. Yu.F. Zabashta, V.I. Kovalchuk, S.V. Gryn. Phase transition and microgel formation in polymer solutions with salt ions. Ukr. J. Phys. 70, 200 (2025).

https://doi.org/10.15407/ujpe70.3.200

19. L.A. Bulavin, A.N. Alekseev, L.N. Garkusha, Yu.F. Zabashta, S.Yu. Tkachev. Application of viscosimetric method to study configurational transitions in glucose aqueous solutions. Ukr. J. Phys. 56, 450 (2011).

20. J. Frenkel. Kinetic Theory of Liquids (Dover Publications, 1955).

21. A. Tialiou, Z.H. Athab, R.T. Woodward, V. Biegler, B.K. Keppler, A.F. Halbus, M.R. Reithofer, J.M. Chin. Fabrication of graded porous structure of hydroxypropyl cellulose hydrogels via temperature-induced phase separation. Carbohydr. Polym. 315, 120984 (2023).

https://doi.org/10.1016/j.carbpol.2023.120984

22. R.S. Dezotti, L.M. Furtado, M. Yee, T.S. Valera, K. Balaji, R.A. Ando, D.F.S. Petri. Tuning the mechanical and thermal properties of hydroxypropyl methylcellulose cryogels with the aid of surfactants. Gels 7, 118 (2021).

https://doi.org/10.3390/gels7030118

23. A.R. Khokhlov, E.E. Dormidontova. Self-organization in ion-containing polymer systems. Phys.-Uspekhi 40, 109 (1997).

https://doi.org/10.1070/PU1997v040n02ABEH000191

24. L.A. Bulavin, N.I. Lebovka, Yu.A. Kyslyi, S.V. Khrapatyi, A.I. Goncharuk, I.A. Mel'nyk, V.I. Koval'chuk. Microstructural, rheological, and conductometric studies of multiwalled carbon nanotube suspensions in glycerol. Ukr. J. Phys. 56, 217 (2011).

25. M. Stoian, T. Maurer, S. Lamri, I. Fechete. Techniques of preparation of thin films: Catalytic combustion. Catalysts 11, 1530 (2021).

https://doi.org/10.3390/catal11121530

26. C. Trinh, Y. Wei, A. Yadav, M. Muske, N. Grimm, Z. Li, L. Thum, D. Wallacher, R. Schl¨ogl, K. Skorupska, R. Schlatmann, D. Amkreutz. Reactor design for thin film catalyst activity characterization. Chem. Eng. J. 477, 146926 (2023).

https://doi.org/10.1016/j.cej.2023.146926

27. X. Yao, H. Chen, H. Qin, Qi-Hang Wu, Huai-Ping Cong, Shu-Hong Yu. Solvent-adaptive hydrogels with lamellar confinement cellular structure for programmable multimodal locomotion. Nat. Commun. 15, 9254 (2024).

https://doi.org/10.1038/s41467-024-53549-y

Published

2025-07-21

Issue

Section

Liquid crystals and polymers

How to Cite

Lamellar Gels: Structural Peculiarities. (2025). Ukrainian Journal of Physics, 70(7), 470. https://doi.org/10.15407/ujpe70.7.470

Most read articles by the same author(s)

1 2 3 4 5 6 > >>