The Transmission Spectrum of the Mixture of CO and HF for the Time-Dependent Density of CO
DOI:
https://doi.org/10.15407/ujpe61.09.0774Keywords:
Fourier spectroscopy, hydrogen fluoride, carbon monoxide, time-dependent densityAbstract
The gas phase spectra of a mixture of hydrogen fluoride (HF) and carbon oxide (CO) are obtained for the interval from 3838 to 3854 cm−1. Using the Fourier transform infrared (FTIR) broadband spectroscopy technique, the arising P-heads of the fundamental and hot bands of OC–HF complex are observed with increasing the pressure of the CO component, while the HF compound has a fixed amount of molecules. The dependence of the integral change in the transmitted intensity on the pressure of carbon monoxide is analyzed in vicinities of the P-heads of the fundamental band at 3939.12 cm−1 and the hot band at 3944.5 cm−1.
References
A.C. Legon, P.D. Soper, and W.H. Flygare, The rotational spectrum, H, 19F nuclear spin–nuclear spin coupling, D nuclear quadrupole coupling, and molecular geometry of a weakly bound dimer of carbon monoxide and hydrogen fluoride, J. Chem. Phys. 74(9), 4944 (1981).
http://dx.doi.org/10.1063/1.441747
G.T. Fraser and A.S. Pine, Isotope effects in the high-resolution infrared spectrum of OC–HF, J. Chem. Phys. 88, 4147 (1988).
http://dx.doi.org/10.1063/1.453821
J. Han, A.L. McIntosh, C.L. Hartz, and J.W. Bevan, A rovibrational analysis of the 1 and 2 bands of OC–DF by supersonic jet FTIR spectroscopy, Chem. Phys. Lett. 264, 411 (1997).
http://dx.doi.org/10.1016/S0009-2614(96)01333-4
Z. Wang and J.W. Bevan, Diode laser spectroscopy of the hydrogen bond vibration 2 OC–HF in a continuous wave supersonic jet, J. Chem. Phys. 91, 3335 (1989).
http://dx.doi.org/10.1063/1.457642
K. McMillan, D. Bender, M. Eliades, D. Danzeiser, B.A. Wofford, and J.W. Bevan, Supersonic molecular beam and static gas phase spectroscopy of intermolecular hot bands associated with 1 16O 12C–1H19F, Chem. Phys. Lett. 152, 87 (1988).
http://dx.doi.org/10.1016/0009-2614(88)87333-0
G.A. Jeffrey and W. Saenger, Hydrogen Bonding in Biological Structures (Springer, Berlin, 1991) [ISBN: 3-540-50839-2].
http://dx.doi.org/10.1007/978-3-642-85135-3
P. Hobza, in Annual Reports on the Progress of Chemistry, Section C, Physical Chemistry (Royal Soc. Chemistry, Cambridge, 2004), p. 3.
J.E.D. Bene and M.J.T. Jordan, Vibrational spectroscopy of the hydrogen bond: An ab initio quantum-chemical perspective, Int. Rev. Phys. Chem. 18, 119 (1999).
http://dx.doi.org/10.1080/014423599230026
G. Gilli and P. Gilli, Towards an unified hydrogen-bond theory, J. Mol. Struct. 552, 1 (2000).
http://dx.doi.org/10.1016/S0022-2860(00)00454-3
V.K. Pogorelyi, Weak hydrogen bonds Russ. Chem. Rev. 46, 316 (1977).
http://dx.doi.org/10.1070/RC1977v046n04ABEH002134
G. Gilli and P. Gilli, The Nature of the Hydrogen Bond: Outline of a Comprehensive Hydrogen Bond Theory (Oxford Univ. Press, Oxford, New York, 2009).
http://dx.doi.org/10.1093/acprof:oso/9780199558964.001.0001
Y. Mar’echal, The Hydrogen Bond and the Water Molecule: the Physics and Chemistry of Water, Aqueous and Bio Media (Elsevier, Amsterdam, 2007).
J.C. Speakman, The Hydrogen Bond and Other Intermolecular Forces (Chemical Society, London, 1975) [ISBN 10: 085186919X].
P. Schuster, G. Zundel, and C. Sandorfy, The Hydrogen Bond: Recent Developments in Theory and Experiments (North-Holland, Amsterdam, 1976).
T.A. Dolenko et al., Raman Spectroscopy of Water-Ethanol Solutions: The Estimation of Hydrogen Bonding Energy and the Appearance of Clathrate-like Structures in Solutions, J. Phys. Chem. A 119, 10806 (2015).
http://dx.doi.org/10.1021/acs.jpca.5b06678
M.S. Ghoraishi et al., Clustering mechanism of ethanol-water mixtures investigated with photothermal microfluidic cantilever deflection spectroscopy, Sci. Reps. 6, 23966 (2016).
http://dx.doi.org/10.1038/srep23966
E.K. Kyr¨o, P. Shoja-Chaghervand, K. Mcmillan, M. Eliades, D. Danzeiser, and J.W. Bevan, Rotational-vibration analysis of the = 0, 6 + 1 − 6 subband in the hydrogen-bonded system O12C···1H19F, J. Chem. Phys. 79, 78 (1983).
http://dx.doi.org/10.1063/1.445516
K.W. Jucks and R.E. Miller, The effect of vibrational state mixing on the predissociation lifetime of 1 excited OC—HF, J. Chem. Phys. 86, 6637 (1987).
http://dx.doi.org/10.1063/1.452410
Mohsen Razavy, Quantum Theory of Tunneling (World Scientific, Singapore, 2003) [ISBN: 981-238-018-3].
L.A. Rivera-Rivera, Z. Wang, B.A. McElmurry, R.R. Lucchese, J.W. Bevan, and G. Kanschat, Morphing a Vibrationally-Complete Ground State Potential for the Hydrogen Bond OC–HF, Chem. Phys. 390, 42 (2011).
Downloads
Published
Issue
Section
License
Copyright Agreement
License to Publish the Paper
Kyiv, Ukraine
The corresponding author and the co-authors (hereon referred to as the Author(s)) of the paper being submitted to the Ukrainian Journal of Physics (hereon referred to as the Paper) from one side and the Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, represented by its Director (hereon referred to as the Publisher) from the other side have come to the following Agreement:
1. Subject of the Agreement.
The Author(s) grant(s) the Publisher the free non-exclusive right to use the Paper (of scientific, technical, or any other content) according to the terms and conditions defined by this Agreement.
2. The ways of using the Paper.
2.1. The Author(s) grant(s) the Publisher the right to use the Paper as follows.
2.1.1. To publish the Paper in the Ukrainian Journal of Physics (hereon referred to as the Journal) in original language and translated into English (the copy of the Paper approved by the Author(s) and the Publisher and accepted for publication is a constitutive part of this License Agreement).
2.1.2. To edit, adapt, and correct the Paper by approval of the Author(s).
2.1.3. To translate the Paper in the case when the Paper is written in a language different from that adopted in the Journal.
2.2. If the Author(s) has(ve) an intent to use the Paper in any other way, e.g., to publish the translated version of the Paper (except for the case defined by Section 2.1.3 of this Agreement), to post the full Paper or any its part on the web, to publish the Paper in any other editions, to include the Paper or any its part in other collections, anthologies, encyclopaedias, etc., the Author(s) should get a written permission from the Publisher.
3. License territory.
The Author(s) grant(s) the Publisher the right to use the Paper as regulated by sections 2.1.1–2.1.3 of this Agreement on the territory of Ukraine and to distribute the Paper as indispensable part of the Journal on the territory of Ukraine and other countries by means of subscription, sales, and free transfer to a third party.
4. Duration.
4.1. This Agreement is valid starting from the date of signature and acts for the entire period of the existence of the Journal.
5. Loyalty.
5.1. The Author(s) warrant(s) the Publisher that:
– he/she is the true author (co-author) of the Paper;
– copyright on the Paper was not transferred to any other party;
– the Paper has never been published before and will not be published in any other media before it is published by the Publisher (see also section 2.2);
– the Author(s) do(es) not violate any intellectual property right of other parties. If the Paper includes some materials of other parties, except for citations whose length is regulated by the scientific, informational, or critical character of the Paper, the use of such materials is in compliance with the regulations of the international law and the law of Ukraine.
6. Requisites and signatures of the Parties.
Publisher: Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine.
Address: Ukraine, Kyiv, Metrolohichna Str. 14-b.
Author: Electronic signature on behalf and with endorsement of all co-authors.
.png){kind=small}
